EVIDENCE FOR NITROGEN MIGRATION IN THE BENZILIC ACID REARRANGEMENT OF ALLOXAN AND DERIVATIVES
Journal Article
·
· Journal of the American Chemical Society (U.S.)
The benzilic acid rearrangements of alloxan(I) to alloxanic acid(H) was recently the subject of a kinetic study. Tracer studies with C/sup 1//sup 4/ show that the nitrogen-carbon shift takes place to the exclusion of the carbon- carbon shift during rearrangement of alloxan and several of its derivatives under widely differing conditions of pH. Data and method of rearrangement are given. (P.C.H.)
- Research Organization:
- Univ. of Delaware, Newark
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-15-020705
- OSTI ID:
- 4090020
- Journal Information:
- Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 83; ISSN JACSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
Similar Records
THE REARRANGEMENT OF ALLOXAN AND ITS DERIVATIVES (thesis)
The acid-catalyzed rearrangement of cinenic acid. V. evidence for a decarbonylation-rearbonylation mechanism
Kinetics and mechanisms of 1,5-dihydroflavin reduction of carbonyl compounds and flavin oxidation of alcohols. III. Oxidation of benzoin by flavin and reduction of benzil by 1,5-dihydroflavin
Technical Report
·
Fri Jun 01 00:00:00 EDT 1962
·
OSTI ID:4837882
The acid-catalyzed rearrangement of cinenic acid. V. evidence for a decarbonylation-rearbonylation mechanism
Journal Article
·
Tue Jan 19 23:00:00 EST 1960
· Journal of the American Chemical Society (U.S.)
·
OSTI ID:4176465
Kinetics and mechanisms of 1,5-dihydroflavin reduction of carbonyl compounds and flavin oxidation of alcohols. III. Oxidation of benzoin by flavin and reduction of benzil by 1,5-dihydroflavin
Journal Article
·
Tue Nov 23 23:00:00 EST 1976
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:7317564