CHEMICAL EFFECTS OF IONIZING RADIATIONS ON AQUEOUS SOLUTIONS OF VANADIUM. III. EFFECT OF $alpha$ PARTICLES ON ACID SOLUTIONS OF TETRAVALENT AND PENTAVALENT VANADIUM

Journal Article · Tue Nov 01 04:00:00 EST 1960 · Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides

OSTI ID:4082676

S>At sufficient doses the irradiation, by alpha particles from dissolved Po/sup 210/, of sulfuric acid solutions of tetravalent and pentavalent salts leads to a stationary state between these two valences, whereas the initial reduction of V/sup 5+/ is accompanied by peroxidation. These various phenomena were interpreted by use of the hypothesis suggested in an analogous study with gamma raye (J. chim. phys. 55:772(1958)). The yields of radical and molecular products during the radiolysis of these solutions by 5.3-Mev alpha particles and the kinetic data on the reactions of the products with vanadium salts were detemined. (tr-auth)

• Research Organization: Originating Research Org. not identified
• NSA Number: NSA-15-010988
• OSTI ID: 4082676
• Journal Information: Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides, Journal Name: Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides Vol. Vol: 57; ISSN JCPQA
• Country of Publication: Country unknown/Code not available
• Language: French

Related Subjects

ACIDS
ALPHA PARTICLES
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
FREE RADICALS
GAMMA RADIATION
IRRADIATION
OXIDATION
POLONIUM 210
RADIATIONS
REACTION KINETICS
REDUCTION
SALTS
SOLUTIONS
SULFURIC ACID
VANADIUM
WATER