Plutonium Extraction by the Formation of Insoluble Salts; EXTRACTION DU PLUTONIUM PAR FORMATION DE SELS INSOLUBLES
The aim of this work is to convert Pu IV nitrate in solution into an insoluble salt. Three methods have been studied: 1) the conventional oxalic acid method was improved; 2) precipitation with 8-hydroxyquinoline was tried; 3) the hydrogen peroxide method was adapted to the eluates of the ionic resins from Marcoule. The yield from the oxalic process has been increased (loss of Pu in the mother-liquor brought from 200 mg/l to 20 mg/l). The study of Pu IV precipitation by 8-hydroxyquinoline has shown that the yield is excellent (Pu concentration in the mother-liquor less than 5 mg/h), but decontamination from impurities is nil. Finally, experiments on the precipitation by hydrogen peroxide of Pu IV solutions at the concentrations normally obtained from the anionic resins at Marcoule have given us good yields (Pu concentration in the mother-liquor less than 7 mg/l), and the purification is better than that obtained by oxalic acid (1000 ppm total impurities after a precipitation). (author)
- Research Organization:
- Commissariat a l' Energie Atomique. Centre d' Etudes Nucleaires, Saclay (France)
- NSA Number:
- NSA-15-011038
- OSTI ID:
- 4082518
- Report Number(s):
- CEA-1592
- Resource Relation:
- Other Information: Thesis submitted to Conservatoire National des Arts et Metiers, Paris, France
- Country of Publication:
- France
- Language:
- English
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