ELECTRON SPIN RESONANCE OF GAMMA-RAY IRRADIATED SINGLE CRYSTALS OF SODIUM NITRITE

Journal Article · Sun Mar 01 04:00:00 EST 1964 · Journal of Chemical Physics (U.S.)

DOI:https://doi.org/10.1063/1.1725314· OSTI ID:4081805

Tateno, J; Gesi, K

Single crystals of sodium nitrite were irradiated with Co/sup 60/ gamma rays of about 10/sup 9/ r at room temperature and studied by ESR method. The spectrum consists of a triplet and a quintet associated with different paramagnetic species; the former is believed to be NO/sub 2/ and the latter N/sub 2/0/sub 4/. From the analysis of the anisotropy of the hyperfine tensor the molecular plane of NO/sub 2/ lies in the crystal ac plane. Molecular orbital of the unpaired electron of N/sub 2/O/sub 4/ was also calculated. (auth)

• Research Organization: Japan Atomic Energy Research Inst., Tokyo
• Sponsoring Organization: USDOE
• NSA Number: NSA-18-013863
• OSTI ID: 4081805
• Journal Information: Journal of Chemical Physics (U.S.), Journal Name: Journal of Chemical Physics (U.S.) Vol. Vol: 40; ISSN JCPSA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ANIONS
ANISOTROPY
CHEMISTRY
COBALT 60
CONFIGURATION
DEFECTS
DIAGRAMS
ELECTRON SPIN RESONANCE
ELECTRONS
ENERGY LEVELS
FREE RADICALS
GAMMA RADIATION
GAMMA SOURCES
IONIZATION
IRRADIATION
LATTICES
MAGNETIC RESONANCE
MAGNETISM
MEASURED VALUES
MOLECULES
MONOCRYSTALS
NITROGEN OXIDES
NITROUS ACID
NUMERICALS
OSCILLATIONS
PARAMAGNETISM
RADIATION CHEMISTRY
RADIATION DOSES
RADIATION EFFECTS
SODIUM COMPOUNDS
SPECTRA
SPIN
TENSORS
VECTORS