EXPLANATION OF SOME 'FORBIDDEN' TRANSITIONS IN PARAMAGNETIC RESONANCE
Journal Article
·
· Proc. Phys. Soc. (London)
The abnormal intensity of some "forbidden" hyperfine transitions in the paramagnetic resonance spectra of ions with S = 1 or more is shown to be due to cross terms in the spin hamiltonian. These arise from off-diagonal terms in the electronic and nuclear interactions, and the computed transition intensities agree closely with measurements on vanadium fluosilicate. In a powder an apparent doubling of the hyperfine transitions is shown to be due to the combined effect of these terms and others due solely to the electronic splitting. (auth)
- Research Organization:
- Clarendon Lab., Oxford
- NSA Number:
- NSA-15-011852
- OSTI ID:
- 4081760
- Journal Information:
- Proc. Phys. Soc. (London), Journal Name: Proc. Phys. Soc. (London) Vol. Vol: 77
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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