Interaction of triplet silicon difluoride with paramagnetic molecules

Journal Article · Tue Dec 31 23:00:00 EST 1974 · J. Chem. Soc. (London), Chem. Commun., pp. 155-157

DOI:https://doi.org/10.1039/c39750000156· OSTI ID:4079714

Zeck, O F; Su, Y Y; Tang, Y N

Recoil $sup 31$Si atom reactions with Pf$sub 3$ resulted in the formation of both singlet and triplet $sup 31$SiF$sub 2$ in the ratio 1.0:3.5 where the triplet species was found to interact with paramagnetic molecules forming $sup 31$SiF$sub 2$-donor complexes towards buta-1,3-diene. (auth)

• Research Organization: Texas A and M Univ., College Station
• NSA Number: NSA-33-028590
• OSTI ID: 4079714
• Journal Information: J. Chem. Soc. (London), Chem. Commun., pp. 155-157, Journal Name: J. Chem. Soc. (London), Chem. Commun., pp. 155-157; ISSN JCCCA
• Country of Publication: United Kingdom
• Language: English

Related Subjects

*SILICON FLUORIDES-- TRIPLETS
400701* --Chemistry--Radiochemistry & Nuclear Chemistry--Hot- Atom Chemistry
BUTADIENE
CHEMICAL REACTION YIELD
HOT ATOM CHEMISTRY
N40410* --Chemistry--Radiochemistry & Nuclear Chemistry--Hot Atom Chemistry
NITROGEN OXIDES
OXYGEN
PARAMAGNETISM
PHOSPHORUS FLUORIDES
RECOILS
SILICON 31