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I. DIFFUSION OF WEAK ELECTROLYTES IN AQUEOUS SOLUTIONS. II. DIFFUSION OF HYDROCHLORIC ACID IN AQUEOUS SOLUTIONS (thesis)

Technical Report ·
OSTI ID:4073270
The dillusion coefficients were determined for acetic acid at 9.03 x 10/ sup -4/ to 5.55 x 10/sup -2/M and chloroacetic acid at 1.08 x 10/sup -3/ to 3.09 x 10/sup -3/M in aqueous solutions. The experimental method used was the Harned conductometric technique. The experimental diffusion coefficients were found to be higher than those which could be calculated from theories assuming no interactions between ionic and molecular species other than the dissociation equilibrium. At concentrations large enough to reduce ionization to values of 1% or less, the calculated and experimental values were found to approach each other. Results are given of preliminary investigations on diffusion of hydrochloric acid in dilute solutions. (B.O.G.)
Research Organization:
Yale Univ., New Haven
NSA Number:
NSA-15-012908
OSTI ID:
4073270
Report Number(s):
TID-11805
Country of Publication:
United States
Language:
English

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