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PRESSURE EFFECT ON COLOR CENTERS IN RbF, RbCl, RbBr AND Csl

Journal Article · · Phys. Chem. Solids
The absorption spectra of the F and M centers in RbF, RbCl, HbBr, and CsI were investigated as a function of pressure. In addition to the F and M bands, the No. 3 band and some other unidentified bands were also observed. The experiments were conducted at room temperature with both electrolytically and additively colored crystals. Frequency shifts were observed under pressures up to 10000 atm for the absorption spectra of RbCl and RbBr and up to 50000 atm for the absorption spectra of RbF and CsI. In RbF a phase transition appears at 33000 atm. The pressure dependence of the frequency shift in the rubidium halides is similar to that in the potassium halides. (auth)
Research Organization:
Univ. of Maryland, College Park
NSA Number:
NSA-18-010090
OSTI ID:
4070586
Journal Information:
Phys. Chem. Solids, Journal Name: Phys. Chem. Solids Vol. Vol: 24
Country of Publication:
Country unknown/Code not available
Language:
English

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