THE DETECTION OF RADIOISOTOPES IN URINE. PART II

Journal Article · Sun Sep 01 04:00:00 EDT 1963 · Pharmazie (West Germany)

OSTI ID:4068645

Schulte, K E; Henke, G

A review of methods for identification and separation of radioisotopes is presented. The characterization of radionuclides of a urine sample by desermination of the type and energy of the radiation is discussed. Separation of radioactive cations of urine is reviewed, with particular attention to qualitative separation of isotope mixtures, preparation of the sample for cation separation, and separation of radioactive cations of urine by precipitation of groups. Analysis of the cations in a model sample of urine is tabulated. Great emphasis is placed on the use of paper chromatography of inorganic ions; a general review is given of this topic with emphasis on the separation of radioisotopes. Results are illustrated and R/sub f/ values given for various groups with the following ascending solvents: HCl group (Hg(I), Tl(I), Ag, Pb), 10% NH/sub 4/OAc; reduction group (Te, Se, Au, Tl(III)), EtOH-2N AcOH, 4 : 1 (vol); H/sub 2/S group I (Pb, Cd, Cu, Bi, Hg), tert-BuOH- acetone - H/sub 2/O- acetylacetone HNO/sub 3/, 49:33:10:5:3 (vol); H/sub 2/S group II (Sb, Mo, As, Sn), n-BuOH saturated with 2.16N HCl; urotropine group I (Zr, Ce, Fe), acetone- n- BuOH- HCl(25%), 5 : 5 : 6 (vol); urotropine group II (Cr, V, Be, U), acetone-tent- BuOH- HCl (25%)- acetylacetone, 33: 43: 19: 5 (vol); (NH/sub 4/)2S group (Ni, Mn, Co, Zn), acetone- H/sub 2/O- HCl(36%), 87: 5: 8 (vol); alkaline eanth group (Ba, Sr, Ca), MeOH- HCl(25%) - H/sub 2/O, 8: 1: 1 (vol); alkali metals (K, Rb, Cs, NH/ sub 4/), HCl(36%) - MeOHisobutyl methyl ketone- n-BuOH, 55: 35: 5: 5 (vol). The analytical procedure for these determinations is given. (BBB)

• Research Organization: Westfalische Wilhelms-Universitat, Munster, Ger.
• NSA Number: NSA-18-015988
• OSTI ID: 4068645
• Journal Information: Pharmazie (West Germany), Journal Name: Pharmazie (West Germany) Vol. Vol: 18; ISSN PHARA
• Country of Publication: Country unknown/Code not available
• Language: German

Related Subjects

ACETONE
ACETYL RADICALS
ALCOHOLS
AMINES
AMMONIUM COMPOUNDS
ANTIMONY ISOTOPES
ARSENIC ISOTOPES
BARIUM ISOTOPES
BERYLLIUM ISOTOPES
BISMUTH ISOTOPES
BUTANOL
CADMIUM ISOTOPES
CALCIUM ISOTOPES
CERIUM ISOTOPES
CESIUM ISOTOPES
CHEMISTRY
CHROMIUM ISOTOPES
COBALT ISOTOPES
COPPER ISOTOPES
ETHANOL
ETHERS
GOLD ISOTOPES
HYDROCHLORIC ACID
HYDROGEN SULFIDES
HYDROXIDES
IRON ISOTOPES
ISOTOPE SEPARATION
KETONES
LEAD ISOTOPES
MANGANESE ISOTOPES
MERCURY ISOTOPES
MOLYBDENUM ISOTOPES
NICKEL ISOTOPES
NITRIC ACID
ORGANIC NITROGEN COMPOUNDS
POTASSIUM ISOTOPES
PRECIPITATION
QUANTITATIVE ANALYSIS
RADIOISOTOPES
REDUCTION
RUBIDIUM ISOTOPES
S