A Separation of Beryllium from Aluminum, Trivalent Iron, Yttrium, Cerium, and the Rare Earths by Cation Exchange Chromatography

Journal Article · Fri Mar 31 23:00:00 EST 1961 · Analytical Chemistry

DOI:https://doi.org/10.1021/ac60172a018· OSTI ID:4062929

Strelow, F. W. E.

A systematic study of the absorbabilities of cations with AG 50W-XS resin in hydrochloric and nitric acids indicated that the difference in the equilibrium distribution coefficients among beryllium and a number of other cations is large enough to warrant a good separation. This fact was used to develop a cation exchange chromatographic procedure for the separation of Be from Al(lII), Fe(III), Y(III), and Ce(IlI). Other elements that are completely separated include Sr(II), Ba(II), Ga(III), La(IlI), and the rare earths, Zr(IV) and Th(IV). A number of elements, such as Cd(II), Sn(IV), S(IV), Hg(II), V(V), Mo(V), Au(III), As(III), and Sb(III), can be eluted from the column with 0.5N HCl before the separation of beryllium from the more strongly absorbed elements is started. The method of separation is applied to the determination of beryllium in a gadolinite ore.

• Research Organization: South African Council for Scientific and Industrial Research, Pretoria
• Sponsoring Organization: USDOE
• NSA Number: NSA-15-014216
• OSTI ID: 4062929
• Journal Information: Analytical Chemistry, Journal Name: Analytical Chemistry Journal Issue: 4 Vol. 33; ISSN 0003-2700
• Publisher: American Chemical Society (ACS)
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ALUMINUM
ANTIMONY
ARSENIC
BARIUM
BERYLLIUM
CADMIUM
CATIONS
CERIUM
CHEMISTRY
CHROMATOGRAPHY
GALLIUM
GOLD
HYDROCHLORIC ACID
ION EXCHANGE
IRON
LANTHANUM
MERCURY
MOLYBDENUM
NITRIC ACID
ORES
QUANTITATIVE ANALYSIS
RARE EARTHS
RESINS
SELENIUM
SEPARATION PROCESSES
STRONTIUM
THORIUM
TIN
VANADIUM
YTTRIUM
ZIRCONIUM