THE EQUILIBRIUM 2/3Bi(l) + 1/3BiI$sub 3$(g) = BiI(g)
Journal Article
·
· Journal of Physical Chemistry (U.S.)
S>The equilibrium 2/3 Bi(l) + 1/3 BiI/sub 3/(g) = BiI(g) was studied by a transpirat ion technique over the temperature range 545 to 735 deg and the pressure range 0.1 to 50 mm. The enthalpy change for the reaction was 21 kcal and the standard entropy 16 eu at mid-temperature. An excess pressure of reduced Bi species in the higher pressure range was interpreted as due to the formation of a polymer, Bi/sub n/I/sub n/. (auth)
- Research Organization:
- Stanford Research Inst., Menlo Park, Calif.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-15-012944
- OSTI ID:
- 4061687
- Journal Information:
- Journal of Physical Chemistry (U.S.), Journal Name: Journal of Physical Chemistry (U.S.) Vol. Vol: 65; ISSN JPCHA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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