Solubility of hydrogen, carbon monoxide, and 1-octene in various solvents and solvent mixtures

Journal Article · Thu Oct 31 23:00:00 EST 1996 · Journal of Chemical and Engineering Data

DOI:https://doi.org/10.1021/je960024e· OSTI ID:404526

Purwanto,; Deshpande, R M; Chaudhari, R V; Delmas, H ^[1]

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1. ENSIGC, Toulouse (France)

The solubility of H{sub 2} has been measured as a function of pressure in ethanol + water and various solvents at (298 and 323) K. The results are compared with theoretical predictions for H{sub 2} indifferent solvents and some mixtures and found to agree within {+-} 10% error, except for acetonitrile. The solubility of CO in 1-octene has also been measured. Liquid-liquid equilibrium for the 1-octene + water + ethanol system was measured at (298 and 323) K, but the predictions of these data by the UNIFAC-UNIQUAC models were not found to be satisfactory, except for higher 1-octene concentrations in water (> 6% w/w) for which the predictions were within 10% error.

• OSTI ID: 404526
• Journal Information: Journal of Chemical and Engineering Data, Journal Name: Journal of Chemical and Engineering Data Journal Issue: 6 Vol. 41; ISSN JCEAAX; ISSN 0021-9568
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
08 HYDROGEN
54 ENVIRONMENTAL SCIENCES
AQUEOUS SOLUTIONS
CARBON MONOXIDE
EQUATIONS OF STATE
HYDROGEN
OCTENES
ORGANIC SOLVENTS
SOLUBILITY