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CHEMICAL PROPERTIES OF SOME VANADIUM COMPOUNDS IN ALKALINE CHLORIDE MELTS (in French)

Journal Article · · Bull. soc. chim. France
OSTI ID:4035392
The values of the solubility products of some oxides in molten LiCl-KCl eutectic are given. After a discussion of the probable forms in which the different oxidation states of V exist, the constants are given for some complexes and for the O/sup 2-/ ion measured semi-quantitatively. These made it possible to establish the theoretical diagram (E,pO/sup 2-/) for the oxydo-reduction system V/sup 4+//V/sup 5+/. Chemical reactions illustrate the predictions possible from a knowledge of the diagram and the constants given. (auth)
Research Organization:
Ecole de Physique et Chimie, Paris
NSA Number:
NSA-15-023497
OSTI ID:
4035392
Report Number(s):
(AEC-tr-5081) in RDA; CEA-1946
Journal Information:
Bull. soc. chim. France, Journal Name: Bull. soc. chim. France
Country of Publication:
Country unknown/Code not available
Language:
French