Existence of H$sup 2-$, a relatively long-lived doubly charged negative atomic hydrogen ion

Journal Article · Mon Mar 15 04:00:00 EST 1976 · J. Chem. Phys., v. 64, no. 6, pp. 2466-2480

OSTI ID:4020986

Schnitzer, R; Anbar, M

Doubly charged negative hydrogen ions H$sup 2-$ and D$sup 2-$ have been indirectly observed in a tandem mass spectrometer using a hollow cathode duoplasmatron ion source. The half-life of these doubly charged ions, determined in a number of drift time experiments, is 23+-4 nsec. The existence of these ions is concluded from a velocity, momentum, and energy analysis of hydride ions produced in the autodetachment process: X$sup 2-$$Yields$$X$$sup -$+e (X=H,D). (AIP)

• Research Organization: Mass Spectrometry Research Center, Stanford Research Institute, Menlo Park, California 94025
• NSA Number: NSA-33-031086
• OSTI ID: 4020986
• Journal Information: J. Chem. Phys., v. 64, no. 6, pp. 2466-2480, Journal Name: J. Chem. Phys., v. 64, no. 6, pp. 2466-2480; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

*DEUTERIUM IONS-- MASS SPECTRA
*HYDROGEN IONS-- MASS SPECTRA
640302* --Physics Research--Atomic
Molecular & Chemical Physics--Atomic & Molecular Properties
ANIONS
ELECTRON DETACHMENT
HALF-LIFE
N60200* --Physics (Atomic & Molecular)--Atomic & Molecular Properties