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Channel Mixing Effects in the Dissociative Recombination of H{sup +}{sub 3} with Slow Electrons

Journal Article · · Physical Review Letters
We discuss the low-energy dissociative recombination of H{sup +}{sub 3} , which strongly influences the abundance of this ion in diffuse interstellar molecular clouds. The kinetic couplings between the ionization continuum and the dissociative ground state of H{sub 3} have been used as input to a two-dimensional wave packet calculation of dissociation dynamics. The cross section obtained for direct dissociative recombination is much smaller than the latest experimental results. However, a multichannel quantum defect treatment shows that an indirect mechanism via bound Rydberg states of H{sub 3} prevails for this process.
Sponsoring Organization:
(US)
OSTI ID:
40205885
Journal Information:
Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 18 Vol. 85; ISSN 0031-9007
Publisher:
The American Physical Society
Country of Publication:
United States
Language:
English

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