Motional Effect in Surface Sum-Frequency Vibrational Spectroscopy
Journal Article
·
· Physical Review Letters
Fast orientational motion of molecules at a surface can affect the sum-frequency vibrational spectra of the surface. Calculation shows that the effect is significant if the molecular orientation varies over a broad range within the vibrational relaxation time. The stretch vibration of the free OH bonds at the vapor/water interface is used to illustrate the importance of the effect.
- Sponsoring Organization:
- (US)
- OSTI ID:
- 40205849
- Journal Information:
- Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 21 Vol. 86; ISSN 0031-9007
- Publisher:
- The American Physical Society
- Country of Publication:
- United States
- Language:
- English
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