Doping by metal-mediated epitaxy: Growth of As delta-doped Si through a Pb monolayer
In molecular-beam epitaxy a monolayer of Pb on the Si(111) surface induces single-crystal growth at temperatures well below those required for similar growth on a bare surface. We demonstrate that the suppression of dopant segregation at the lower temperatures attainable by Pb-mediated growth allows the incorporation of As donors at concentrations reaching a few atomic percent. When Pb and Si are deposited on an As-terminated Si(111) substrate at 350{sup o}C, the Pb segregates to the surface without doping the Si film while the As is buried within nanometers of the substrate--film interface. The resulting concentration of electrically active As, 1.8x10{sup 21} cm{sup -3}, represents the highest concentration of As donors achieved by any delta-doping or thin-film deposition method.
- Sponsoring Organization:
- (US)
- OSTI ID:
- 40205251
- Journal Information:
- Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 11 Vol. 78; ISSN 0003-6951
- Publisher:
- The American Physical Society
- Country of Publication:
- United States
- Language:
- English
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