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Effect of Li doping on the charge ordering state of La{sub 0.5}Ca{sub 0.5}MnO{sub 3}

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.1358346· OSTI ID:40204076

The effect of Li doping on the charge ordering (CO) state in perovskite-type manganates La{sub 0.5}Ca{sub 0.5{minus}x}Li{sub x}MnO{sub 3} with x=0, 0.05, 0.1, 0.15, 0.2 is investigated by transport and magnetic property measurements. The resistivity of the samples decreases with the increase of the Li-doped level. As x{ge}0.1, the insulator{endash}metal (IM) transition has been induced. Accompanying the variation of transport properties, the sample undergoes the variation from antiferromagnetic order for x{lt}0.05 to ferromagnetic (FM) order for x{ge}0.1. The experimental results indicate that the Li doping can destroy the CO state and induce the FM metallic (FMM) phase. These phenomena can be interpreted in terms of the strong competition between the CO state and FM phase induced by the Li{sup +} ions substitution for the Ca{sup 2+} ions. {copyright} 2001 American Institute of Physics.

Sponsoring Organization:
(US)
OSTI ID:
40204076
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 11 Vol. 89; ISSN 0021-8979
Publisher:
The American Physical Society
Country of Publication:
United States
Language:
English

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