THE MAGNITUDE OF THE PRIMARY KINETIC ISOTOPE EFFECT FOR COMPOUNDS OF HYDROGEN AND DEUTERIUM
A review is given of small deuterium isotope effects, the first approximation for the calculation of the ratio kH/k/sub D/, experimental data, some general and special cases, and the qualitative and quantitative aspects of the theory. The theory is discussed in terms of carbon-hydrogen and carbon- deuterium bonds, but will also apply to bonds with other elements and, by a simple extension, to compounds of tritium. (P.C.H.)
- Research Organization:
- Harvard Univ., Cambridge, Mass.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-15-025938
- OSTI ID:
- 4009769
- Journal Information:
- Chem. Revs., Journal Name: Chem. Revs. Vol. Vol: 61
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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