Revised Group Additivity Values for Enthalpies of Formation (at 298 K) of Carbon{endash}Hydrogen and Carbon{endash}Hydrogen{endash}Oxygen Compounds
- Thermochemical Kinetics Research, 6507 SE 31st Avenue, Portland, Oregon 97202-8627 (United States)
A program has been undertaken for the evaluation and revision of group additivity values (GAVs) necessary for predicting, by means of Benson{close_quote}s group additivity method, thermochemical properties of organic molecules. This review reports on the portion of that program dealing with GAVs for enthalpies of formation at 298.15 K (hereinafter abbreviated as 298 K) for carbon{endash}hydrogen and carbon{endash}hydrogen{endash}oxygen compounds. A complete database of experimental data for gas, liquid, and crystal (solid) phase enthalpies of formation is presented. The GAVs, ring strain corrections, and non-nearest neighbor interactions derived from the database are presented in tabular form, together with a description of their evaluation and comments on reliability, uncertainties, and missing or questionable data. {copyright} {ital 1996 American Institute of Physics and American Chemical Society.}
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 397486
- Journal Information:
- Journal of Physical and Chemical Reference Data, Journal Name: Journal of Physical and Chemical Reference Data Journal Issue: 6 Vol. 25; ISSN 0047-2689; ISSN JPCRBU
- Country of Publication:
- United States
- Language:
- English
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