Synthesis and properties of ansa-titano- and ansa-zirconocenes

Journal Article · Mon Nov 01 04:00:00 EST 1993 · Russian Chemical Bulletin

DOI:https://doi.org/10.1007/BF00698963· OSTI ID:39250

Churakov, A V; Nifant`ev, I E ^[1]; Urazovskii, I F ^[2]; Nikonov, G I; Yufit, D S; Struchkov, Yu T ^[3]

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1. M.V. Lomonosov Moscow State Univ. (Russian Federation)
2. Institute of Chemical Physics, Chernogolovka (Russian Federation)
3. A.N. Nesmeyanov Institute of Organoelement Compounds, Moscow (Russian Federation)

A series of methyl and allyl derivatives of ansa-titano- and ansa-zirconocenes with isopropylidene or dimethylsilyl bridging groups were synthesized. A dinuclear complex, [Me{sub 2}C(C{sub 5}H{sub 4}){sub 2}]{sub 2}Ti{sub 2}P{sub 2}, resulting from the thermal decomposition of the corresponding dimethyl derivative of ansa-titanocene in the air, was characterized by X-ray diffraction analysis.

• Sponsoring Organization: USDOE
• OSTI ID: 39250
• Journal Information: Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 5 Vol. 42; ISSN RCBUEY; ISSN 1066-5285
• Country of Publication: United States
• Language: English

Related Subjects

40 CHEMISTRY
CHEMICAL PREPARATION
MOLECULAR STRUCTURE
TITANIUM COMPLEXES
X-RAY DIFFRACTION
ZIRCONIUM COMPLEXES