Analysis of emitter material transport in thermionic converter
- Institute for Space and Nuclear Power Studies, Chemical and Nuclear Engineering Department, University of New Mexico, Albuquerque, New Mexico 87131 (United States)
Output power and efficiency of a thermionic converter depend on temperatures, cesiated work functions, and emissivities of electrodes as well as the interelectrode gap size. Operation lifetime of a thermionic converter is directly related to the values as well as the stability of these parameters, which can be seriously altered by the transport of emitter material to the collector during operation. Loss rate of tungsten, a preferred emitter material, by sublimation at typical operating temperatures is small (about 3{times}10{sup 7} atom/cm{sup 2}sec at 2000 K). The loss rate, however, can be several orders of magnitude higher in the presence of gaseous contaminants. Accelerated transport of emitter material to collector surface changes the effective emissivity and work functions of the electrodes, resulting in performance degradation. A phenomenological model was developed to simulate emitter material transport to the collector in the presence of oxygen, water vapor, and carbon oxide contaminants. The model accounts for interaction of these contaminants with both emitter and collector. Model results were in agreement with experimental data and theoretical results of other investigators. An analysis was performed to determine steady-state chemical composition of deposited material onto the collector surface in the presence of H{sub 2}O, O{sub 2}, and H{sub 2} gaseous contaminants. {copyright} {ital 1996 American Institute of Physics.}
- OSTI ID:
- 385468
- Report Number(s):
- CONF-960109--
- Journal Information:
- AIP Conference Proceedings, Journal Name: AIP Conference Proceedings Journal Issue: 1 Vol. 361; ISSN 0094-243X; ISSN APCPCS
- Country of Publication:
- United States
- Language:
- English
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