Infrared multiphoton dissociation of anisole: Production and dissociation of phenoxy radical
Journal Article
·
· Journal of Physical Chemistry
- Univ. of California, Berkeley, CA (United States)
The infrared multiphoton dissociation of anisole in a molecular beam was studied using pulsed CO{sub 2} laser radiation, with the product recoil energy distributions measured using the time-of-flight technique. The only primary process identified was the dissociation into phenoxy and methyl radicals, with the shape of the translational energy distribution of the products revealing a small exit barrier. Under conditions of higher laser fluence, secondary dissociation of the phenoxy radical into carbon monoxide and C{sub 5}H{sub 5} was observed. 28 refs., 9 figs.
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 379465
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 3 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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