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Fission product removal from molten salt using zeolite

Conference ·
OSTI ID:379094
Spent nuclear fuel (SNF) can be treated in a molten salt electrorefiner for conversion into metal and mineral waste forms for geologic disposal. The fuel is dissolved in molten chloride salt. Non-transuranic fission products in the molten salt are ion-exchanged into zeolite A, which is subsequently mixed with glass and consolidated. Zeolite was found to be effective in removing fission product cations from the molten salt. Breakthrough of cesium and the alkaline earths occurred more rapidly than was observed for the rare earths. The effluent composition as a function of time is presented, as well as results for the distribution of fission products along the length of the column. Effects of temperature and salt flow rate are also discussed.
Research Organization:
Argonne National Lab., IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
379094
Report Number(s):
ANL/CMT/CP--87995; CONF-961018--1; ON: DE96014378
Country of Publication:
United States
Language:
English

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