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Vapor-liquid coexistence curves in the critical region and the critical temperatures and densities of 1,1,1,2-tetrafluoroethane (R-134a), 1,1,1-trifluoroethane (R-143a), and 1,1,1,2,3,3-hexafluoropropane (R-236ea)

Journal Article · · Journal of Chemical and Engineering Data
DOI:https://doi.org/10.1021/je960077w· OSTI ID:378018

The vapor-liquid coexistence curves in the critical region of 1,1,1,2-tetrafluoroethane (R-134a), 1,1,1-trifluoroethane (R-143a), and 1,1,1,2,3,3-hexafluoropropane (R-236ea) were measured by a visual observation of the meniscus disappearance in an optical cell. Seventeen saturated-vapor and -liquid densities have been measured for R-134a. Thirty-five saturated-vapor and -liquid densities have been measured for R-143a. Twenty-seven saturated-vapor and -liquid densities have been measured for R-236ea. The level and location of the meniscus, as well as the intensity of the critical opalescence were considered in the determination of the critical temperature and density for each fluid. R-134a was found to have (374.083 {+-} 0.010) K and (509 {+-} 1) kg/m{sup 3}, R-143a, (345.860 {+-} 0.010) K and (434 {+-} 1) kg/m{sup 3}, and R-236ea, (412.375 {+-} 0.015) K and (568 {+-} 1) kg/m{sup 3}.

OSTI ID:
378018
Journal Information:
Journal of Chemical and Engineering Data, Journal Name: Journal of Chemical and Engineering Data Journal Issue: 5 Vol. 41; ISSN 0021-9568; ISSN JCEAAX
Country of Publication:
United States
Language:
English

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