Hydrogen bonding to transition metal fluoride ligands: The synthesis and structure of the bifluoride complex Mo(PMe{sub 3}){sub 4}H{sub 2}F(FHF)
Journal Article
·
· Journal of the American Chemical Society
- Columbia Univ., New York, NY (United States)
In this paper, we describe the synthesis and structural characterization of the bifluoride complex Mo(PMe{sub 3}){sub 4}H{sub 2} F(FHF). In summary, structural and spectroscopic data suggest that the hydrogen-bonding interaction in the bifluoride complex Mo(PMe{sub 3}){sub 4}H{sub 2}F(FHF) may be regarded as `strong`; however, as would be expected on simple electrostatic grounds, the interaction between the covalently bound Mo-F moiety and H-F is weaker than that between F{sup -} and H-F. 25 refs., 1 fig.
- DOE Contract Number:
- FG02-93ER14339
- OSTI ID:
- 374488
- Journal Information:
- Journal of the American Chemical Society, Vol. 118, Issue 31; Other Information: PBD: 7 Aug 1996
- Country of Publication:
- United States
- Language:
- English
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