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Title: Variation of the interfacial shear strength and adhesion of a nanometer-sized contact

Journal Article · · Langmuir
DOI:https://doi.org/10.1021/la9509007· OSTI ID:374465
 [1]; ; ;  [1]
  1. Lawrence Berkeley National Lab., CA (United States)

We observed that the frictional force between a platinum-coated atomic force microscope (AFM) tip and the surface of mica in ultrahigh vacuum (UHV) varies with load in proportion to the contact area predicted by the Johnson-Kendall-Roberts (JKR) theory of adhesive elastic contacts. Using the JKR theory, the interfacial adhesion energy and shear strength can be determined. During the experiment, the tip-sample adhesion unexpectedly decreased by more than one order of magnitude, as did the measured frictional forces. These changes were induced by scanning the tip in contact with the mica sample. We attribute the substantial friction and adhesion decreases to changes of the interface, either structural or chemical, as opposed to changes in bulk structure or properties. The interfacial adhesion energy, {gamma}, dropped by more than one order of magnitude while the shear strength, {tau}, decreased to a lesser extent. Our observations indicate that, for a platinum-coated tip on mica, {tau} {gamma}{sup 0.44}. This is a new observation of a relation between adhesion and friction and is not explained by existing theories. 47 refs., 6 figs., 1 tab.

DOE Contract Number:
AC03-76SF00098
OSTI ID:
374465
Journal Information:
Langmuir, Vol. 12, Issue 13; Other Information: PBD: 26 Jun 1996
Country of Publication:
United States
Language:
English