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Title: Diagenesis of the Machar Field (British North Sea) chalk: Evidence for decoupling of diagenesis in fractures and the host rock

Journal Article · · Journal of Sedimentary Research, Section A: Sedimentary Petrology and Processes
OSTI ID:37115
;  [1]; ;  [2]
  1. Univ. of Cambridge (United Kingdom). Dept. of Earth Sciences
  2. BP Research Centre, Sunbury-on-Thames (United Kingdom)

The Chalk Group (Cretaceous/Tertiary) in the Machar Field (British North Sea) contains both fracture-filling and microcrystalline calcite cements. Modeling of fluid-rock interaction using data on light stable isotopes obtained by whole rock analyses and laser ablation analyses of calcite cements reveal that the fracture and matrix diagenetic systems were largely decoupled. The calcium and carbonate of the fracture-filling calcite cements were derived largely from the adjacent chalk matrix. The fracture diagenetic system had a high water-rock ratio, which maintained a relatively stable water {delta}{sup 18}O ratio during calcite dissolution and precipitation. The chalk matrix, on the contrary, had a low molar water-rock ratio during recrystallization, which resulted in increases in the pore-water {delta}{sup 18}O value during recrystallization at elevated temperatures. This evolution of the pore-water {delta}{sup 18}O value is manifested by highly variable cement {delta}{sup 18}O values. The present-day formation waters of the Machar Field have {sup 87}Sr/{sup 86}Sr ratios significantly higher than the whole rock and fracture-filling cement calcite values, evidence that the chemical composition of the formation waters is not representative of that of the pore waters during chalk recrystallization. Little diagenesis is therefore now occurring in the Machar Field. The diagenetic systems of the chalk matrix and fractures both had a high degree of openness with respect to carbon, because of the introduction of organically derived bicarbonate rather than advection of water through the chalk. The bulk of calcite cementation in fractures and the recrystallization and cementation of the chalk matrix occurred at temperatures in the 80--100 C range, at or just below the present-day reservoir temperature of 97 C.

OSTI ID:
37115
Journal Information:
Journal of Sedimentary Research, Section A: Sedimentary Petrology and Processes, Vol. 65, Issue 1; Other Information: PBD: 2 Jan 1995
Country of Publication:
United States
Language:
English