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Synthesis of aluminate polymer complexes as single-ionic solid electrolytes

Journal Article · · Chemistry of Materials
DOI:https://doi.org/10.1021/cm950388a· OSTI ID:369910
Main-chain anionic polymers with lithium cations, which have oligo(oxyethylene)aluminate chain backbones attached with two side chains of endo-methoxy[oligo(oxyethylene)], were prepared, and their ionic conductivities are reported. The ac conductivity of aluminate polymer complex was about 10{sup -6}-10{sup -7} S cm-11 at room temperature. As the constant current was observed for [Li/aluminate polymer complex/Li] cells under dc electric field, the single-ionic conduction was formed. 9 refs., 2 figs., 4 tabs.
OSTI ID:
369910
Journal Information:
Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 2 Vol. 8; ISSN CMATEX; ISSN 0897-4756
Country of Publication:
United States
Language:
English

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