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Use of ecocores in estimating the biodegradation potential of 4-nonylphenol in freshwater sediments

Conference ·
OSTI ID:367493
;  [1]
  1. Univ. of Wisconsin, Superior, WI (United States). Lake Superior Research Inst.
Ecocores, a type of sediment microcosm used to estimate biodegradation rates in sediments, were used in conjunction with a full-scale mesocosm study to help determine the possible mechanism of degradation of 4-nonylphenol in freshwater sediments. Ecocore and mesocosm sediments displayed very similar nonylphenol concentrations over the duration of the 8-week experiment; neither revealed any signs of nonylphenol degradation. Average nonylphenol concentrations at the beginning of the experiment were not significantly different from concentrations measured at the end of the experiment for both field (9.2 vs. 10.2 {micro}g/g) and ecocore (3.2 vs. 6.4 {micro}g/g) sediments. Mean nonylphenol concentrations remained relatively constant over the duration of the 55-d incubation period in both viable (6.4 {+-} 3.9 {micro}g/g) and sterilized (8.0 {+-} 7.7 {micro}g/g) ecocore sediments. The observation of stable bacterial densities in this study is consistent with the lack of biodegradation of nonylphenol in the sediments of the test system. Ecocores worked well in conjunction with a mesocosm experiment where contaminant loads to the sediment were defined and to some extent controlled. This study indicated that sediment associated 4-nonylphenol is very resistant to microbial degradation within the experimental conditions and 8-week time frame used here.
OSTI ID:
367493
Report Number(s):
CONF-9511137--; ISBN 1-880611-03-1
Country of Publication:
United States
Language:
English

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