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Title: Determination of thiaarenes and polycyclic aromatic hydrocarbons in workplace air of an aluminum reduction plant

Journal Article · · Environmental Science and Technology
DOI:https://doi.org/10.1021/es981151t· OSTI ID:354334
; ;  [1]
  1. Stockholm Univ. (Sweden). Dept. of Analytical Chemistry

Quantitation of a variety of tetra-, penta-, and hexacyclic aromatic sulfur heterocycles (thiaarenes) in workplace air of an aluminum reduction plant has been made by help of gas chromatography with atomic emission detection (GC-AED). Personal exposure to those thiaarenes and to polycyclic aromatic hydrocarbons depending on work categories has been evaluated. Summarized concentrations of the thiaarenes investigated have been found to be 0.4--19.0 {micro}g/m{sup 3}. When using sulfur selective AED, samples could be analyzed without a prior separation of the thiaarenes from the PAH. The present data indicate a contribution of thiaarenes to the overall toxicity of coal tar pitch volatiles in this work environment.

OSTI ID:
354334
Journal Information:
Environmental Science and Technology, Vol. 33, Issue 9; Other Information: PBD: 1 May 1999
Country of Publication:
United States
Language:
English