Electrochemical oxidation of single wall carbon nanotube bundles in sulfuric acid

Journal Article · Thu May 27 04:00:00 EDT 1999 · Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical

DOI:https://doi.org/10.1021/jp984362t· OSTI ID:351560

Sumanasekera, G U; Allen, J L; Fang, S L; Loper, A L; Rao, A M; Eklund, P C ^[1]

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1. Univ. of Kentucky, Lexington, KY (United States)

Electrochemical doping of bisulfate ions into single wall carbon nanotube (SWNT) bundles has been studied using coulometry, cyclic voltammetry, mass-uptake measurements, and Raman scattering experiments. A spontaneous charge-transfer reaction is observed prior to the application of an electrochemical driving force, in sharp contrast to previous observations in the graphite-H{sub 2}SO{sub 4} system. A mass increase of the SWNT sample and a concomitant upshift of the Raman-active tangential mode frequency indicate oxidation (i.e., removal of electrons) of the SWNT bundles. In fact, using Raman scattering, the authors were able to separate the spontaneous and electrochemical contributions to the overall charge transfer, resulting in the value of an upshift of 320 cm{sup {minus}1} per hole, per C-atom introduced into the carbon {pi}-band by the bisulfate (HSO{sub 4}{sup {minus}}) dopant. This value may prove to be a universal measure of charge transfer in acceptor-type SWNT compounds. At a critical electrochemical doping, the SWNT bundles are driven into an overoxidation regime, where they are irreversibly oxidized with the formation of C-O covalent bonds, analogous to electrochemical formation of graphite oxides.

• Sponsoring Organization: USDOE, Washington, DC (United States); National Science Foundation, Washington, DC (United States)
• OSTI ID: 351560
• Journal Information: Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical, Journal Name: Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical Journal Issue: 21 Vol. 103; ISSN 1089-5647; ISSN JPCBFK
• Country of Publication: United States
• Language: English

Related Subjects

40 CHEMISTRY
CARBON
CHARGE TRANSPORT
ELECTROCHEMISTRY
EXPERIMENTAL DATA
OXIDATION
RAMAN EFFECT
SCATTERING
SULFURIC ACID
TUBES