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Experimental results of exothermic reaction with concentration gradient catalyst in a solar chemical heat pump

Conference ·
OSTI ID:347594
; ; ;  [1]; ;  [2]
  1. Electrotechnical Lab., Tsukuba, Ibaraki (Japan)
  2. Shibaura Inst. of Tech., Omiya, Saitama (Japan)

Solar chemical heat pump can upgrade the low temperature solar heat about 80 C to about 150--200 C by the reversible chemical reactions of 2-propanol/acetone/hydrogen, which are composed of endothermic and exothermic reactions. In the exothermic process of above reaction, a temperature peak occurs near the inlet of reaction zone in the case of arranging catalyst uniformly. Such a temperature distribution is not suitable for heat exchange. Therefore, the authors arrange the concentration of catalyst gradationally so as not to occur the temperature peak. In this paper, experimental results of exothermic reaction with concentration gradient catalyst in a double tubular exothermic reactor are presented. These results show that the arrangement of concentration gradient catalyst has the possibility about the temperature control in the catalytic reactor.

OSTI ID:
347594
Report Number(s):
CONF-970701--
Country of Publication:
United States
Language:
English