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Polarization switching of and electron emission from lead lanthanum zirconate titanate ceramics

Journal Article · · Journal of the American Ceramic Society
;  [1];  [2];  [3]
  1. Univ. of Missouri, Rolla, MO (United States). Dept. of Ceramic Engineering
  2. Lawrence Livermore National Lab., CA (United States)
  3. Allied Signal Federal Mfg. and Technologies, Kansas City, MO (United States)
This paper focuses on understanding the influence of material properties on the complicated ferroelectric (FE) emission process. Three different compositions in the lead lanthanum zirconate titanate (PLZT) system were chosen for study, based on their widely different dielectric and ferroelectric properties: antiferroelectric (AFE) 2/95/5, normal ferroelectric 8/65/35, and nonferroelectric 15/65/35. Repeatable emission was obtained from the 2/95/5 composition, which could also be modulated at high frequency (200 kHz). The fast AFE {r_reversible} FE phase transition is responsible for the FE emission properties of this material, which is supported by the relationship between the switching current and the emission current. Comparatively, FE emission from the 8/65/35 composition degraded rapidly, which was attributed to decreases in the remanent polarization. No emission signal was detected from the 15/65/35 composition, because no switching activity occurs, which can be interpreted as additional evidence that electron emission from the previously mentioned two compositions was indeed a FE emission process.
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
347470
Journal Information:
Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 3 Vol. 82; ISSN 0002-7820; ISSN JACTAW
Country of Publication:
United States
Language:
English