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Neutron imaging technique for in situ measurement of water transport gradients within Nafion in polymer electrolyte fuel cells

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/1.1391727· OSTI ID:345393
;  [1]; ; ;  [2]
  1. Exxon Research and Engineering, Annandale, NJ (United States)
  2. National Inst. of Standards and Technology, Gaithersburg, MD (United States)

Water transport is an important consideration in the optimization of polymer electrolyte fuel cell (PEFC) performance, affecting both internal resistance and cathode polarization losses. Novel experiments are described using neutron radiography to measure water gradient profiles within Nafion{reg_sign} in an operating PEFC. Preliminary neutron intensity gradients show qualitative agreement with the expected response of membrane water content to changes in feed gas humidification and fuel cell current. Previous experimental measurements of similar water gradients have generally relied on integral measurements such as ac impedance spectroscopy which cannot probe details of the gradient within the membrane. This is one of the first differential measurements of water gradients within Nafion.

Sponsoring Organization:
USDOE, Washington, DC (United States)
OSTI ID:
345393
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 3 Vol. 146; ISSN JESOAN; ISSN 0013-4651
Country of Publication:
United States
Language:
English

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