Impregnated resins containing di-(2-ethylhexyl) thiophosphoric acid for the extraction of palladium(II). 2: Selective palladium(II) recovery from hydrochloric acid solutions
Journal Article
·
· Solvent Extraction and Ion Exchange
- Univ. Politecnica de Catalunya, Barcelona (Spain). Dept. of Chemical Engineering
The extraction of Pd(II) from HCl solutions by impregnated resins containing di(2-ethylhexyl) thiophosphoric acid (DEHTPA or HL) on the Amberlite XAD2 polymeric support has been studied. Graphical and computer analysis with the program LETAGROP-DISTR demonstrated that the Pd(II) extraction can be explained by the formation of metal complexes in the resin phase having the composition PdL{sub 2}(HL){sub 2}. DEHTPA/XAD2 resins extracted Pd(II) in the presence of other metals: Pt(IV), Rh(III), Cu(II), Fe(III) as well as Zn(II). The stripping of Pd(II) loaded on the organic phase and the lifetime of the resins were also investigated.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 343794
- Journal Information:
- Solvent Extraction and Ion Exchange, Journal Name: Solvent Extraction and Ion Exchange Journal Issue: 2 Vol. 17; ISSN 0736-6299; ISSN SEIEDB
- Country of Publication:
- United States
- Language:
- English
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