Structural and optical properties of silver-doped zirconia and mixed zirconia-silica matrices obtained by sol-gel processing

Journal Article · Mon Mar 01 04:00:00 EST 1999 · Chemistry of Materials

DOI:https://doi.org/10.1021/cm980749x· OSTI ID:338388

Gonella, F; Mattei, G; Mazzoldi, P ^[1]; Battaglin, G ^[2]; Quaranta, A ^[3]; De, G ^[4]; Montecchi, M ^[5]

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1. Univ. di Padova (Italy). Dept. di Fisica
2. Univ. di Venezia (Italy). Dept. di Chimica Fisica
3. Univ. di Trento (Italy). Dept. di Ingegneria dei Materiali
4. Central Glass and Ceramic Research Inst., Calcutta (India). Sol-Gel Div.
5. ENEA-Casaccia, Roma (Italy)

The annealing behavior of zirconia and mixed zirconia-silica matrices (with different ZrO{sub 2}/SiO{sub 2} molar ratios) containing silver nanoclusters, synthesized by the sol-gel technique has been investigated. The film samples of the general formula (SiO{sub 2}){sub x}(ZrO{sub 2}){sub (0.9{minus}x)}Ag{sub 0.1} (x = 0, 0.225, 0.45, 0.675, and 0.9) were treated in different atmospheres (air, N{sub 2}, and 5%H{sub 2}-95%N{sub 2}) at temperatures ranging from 200--900 C. The ZrO{sub 2} matrix undergoes a structural phase transition from amorphous to cubic-tetragonal polycrystalline between 400 and 500 C and on further raising the temperature near 600--700 C the monoclinic phase also develops. On the contrary, the ZrO{sub 2}:SiO{sub 2} system remains amorphous up to {approximately}700 C. Ag nanoclusters are formed in all the systems. It has been observed that the change in the ZrO{sub 2}/SiO{sub 2} molar ratio is an effective way to control not only the overall refractive index of the matrix but also the Ag cluster size. The shifting of the surface plasma resonance position of Ag nanoclusters is observed as a function of the refractive indices of the matrix following the Mie theory. Samples were characterized by transmission electron microscopy, Rutherford backscattering spectrometry, and optical spectrometry to correlate the cluster structure to their optical properties.

• OSTI ID: 338388
• Journal Information: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 3 Vol. 11; ISSN CMATEX; ISSN 0897-4756
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ANNEALING
COMPOSITE MATERIALS
CRYSTAL-PHASE TRANSFORMATIONS
OPTICAL PROPERTIES
PHASE STUDIES
SILICA
SILVER
SOL-GEL PROCESS
THIN FILMS
ZIRCONIUM OXIDES