Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions

Dietz, M L; Horwitz, E P; Bartsch, R A; Barrans, Jr, R E; Rausch, D

Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions

Patent · 30 March 1999

OSTI ID:335435

Dietz, M L; Horwitz, E P; Bartsch, R A; Barrans, Jr, R E; Rausch, D

A crown ether cesium ion extractant is disclosed as is its synthesis. The crown ether cesium ion extractant is useful for the selective purification of cesium ions from aqueous acidic media, and more particularly useful for the isolation of radioactive cesium-137 from nuclear waste streams. Processes for isolating cesium ions from aqueous acidic media using the crown ether cesium extractant are disclosed as are processes for recycling the crown ether cesium extractant and processes for recovering cesium from a crown ether cesium extractant solution. 4 figs.

🛈

Search for the full text at the U.S. Patent and Trademark Office

Research Organization:: University of Chicago

Sponsoring Organization:: USDOE, Washington, DC (United States)

DOE Contract Number:: W-31109-ENG-38

Assignee:: ARCH Development Corp., Chicago, IL (United States)

Patent Number(s):: US 5,888,398/A/

Application Number:: PAN: 8-789,653

OSTI ID:: 335435

Country of Publication:: United States

Language:: English

References (26)

Selectivity in Solvent Extraction of Metal ions by Organic Cation Exchangers Synergized by Macrocycles: Factors Relating to Macrocycle size and Structure McDowell, W. J.; Moyer, B. A.; Case, G. N. Solvent Extraction and Ion Exchange, Vol. 4, Issue 2 https://doi.org/10.1080/07366298608917863	journal	January 1986
Separation of137Cs and90Sr from mineralizates of biological materials by dicarbolide of cobalt Koprda, V.; Ščasnár, V.; Galán, P. Journal of Radioanalytical Chemistry, Vol. 80, Issue 1-2 https://doi.org/10.1007/BF02517647	journal	March 1983
Modified crown ether catalysts. 2. Synthesis of alkanoyl-, aroyl-, .alpha.-hydroxyalkyl- and alkylbenzo and alkylcyclohexano crown ethers Stott, Paul E.; Bradshaw, Jerald S.; Parish, W. Wesley The Journal of Organic Chemistry, Vol. 45, Issue 23 https://doi.org/10.1021/jo01311a033	journal	November 1980
Extraction of Cs ⁺ and Sr ²⁺ from HNO ₃ Solution Using Macrocyclic Polyethers Gerow, I. H.; Smith, J. E.; Davis, M. W. Separation Science and Technology, Vol. 16, Issue 5 https://doi.org/10.1080/01496398108068537	journal	June 1981
Solvent Extraction Recovery of Byproduct ¹³⁷ Cs and ⁹⁰ Sr from HNO ₃ Solutions—A Technology Review and Assessment Schulz, W. W.; Bray, L. A. Separation Science and Technology, Vol. 22, Issue 2-3 https://doi.org/10.1080/01496398708068948	journal	February 1987
Modified crown ether catalysts. 1. Synthesis of alkanoyl-, aroyl-, and .alpha.-hydroxyalkylbenzo Crown ethers Parish, W. Wesley; Stott, Paul E.; McCausland, Calvin W. The Journal of Organic Chemistry, Vol. 43, Issue 24 https://doi.org/10.1021/jo00418a006	journal	November 1978
Ion Extraction and Transport by Proton-Ionizable Crown Ethers Brown, Philip R.; Bartsch, Richard A. Inclusion Aspects of Membrane Chemistry https://doi.org/10.1007/978-94-011-3422-4_1	book	January 1991
Determination of Cesium and Rubidium after Extraction with 4- sec -Butyl-2(α-methylbenzyl)phenol. Ross, W. J.; White, J. C. Analytical Chemistry, Vol. 36, Issue 10 https://doi.org/10.1021/ac60216a035	journal	September 1964
Correlation of the Extraction of Strontium Nitrate by a Crown Ether with the Water Content of the Organic Phase* Horwitz, E. P.; Dietz, M. L.; Fisher, D. E. Solvent Extraction and Ion Exchange, Vol. 8, Issue 1 https://doi.org/10.1080/07366299008917994	journal	February 1990
Extraction of Cesium from Acidic Nitrate Media Using Macrocyclic Polyethers : The Role of Organic Phase Water* Dietz, Mark L.; Philip Horwitz, E.; Rhoads, Susan Solvent Extraction and Ion Exchange, Vol. 14, Issue 1 https://doi.org/10.1080/07366299608918323	journal	January 1996
Solvent Extraction of Cesium (and Rubidium) from Ore Liquors with Substituted Phenols Arnold, W. D.; Crouse, D. J.; Brown, K. B. Industrial & Engineering Chemistry Process Design and Development, Vol. 4, Issue 3 https://doi.org/10.1021/i260015a002	journal	July 1965
Liquid-Liquid Extraction of Cesium with 2-Thenoyltrifluoroacetone. Crowther, Peter.; Moore, F. L. Analytical Chemistry, Vol. 35, Issue 13 https://doi.org/10.1021/ac60206a030	journal	December 1963
Selective extraction of cesium from acidic nitrate solutions with didodecylnaphthalenesulfonic acid synergized with bis(tert-butylbenzo)-21-crown-7 McDowell, W. Jack.; Case, Gerald N.; McDonough, Joseph A. Analytical Chemistry, Vol. 64, Issue 23 https://doi.org/10.1021/ac00047a024	journal	December 1992
Investigations of ion-Size-Selective Synergism in Solvent Extraction McDowell, W. J.; Case, G. N.; Aldrup, D. W. Separation Science and Technology, Vol. 18, Issue 14-15 https://doi.org/10.1080/01496398308056112	journal	November 1983
Extraktion des caesiums aus wässrigen lösungen durch nitrobenzol-lösung von dipikrylamin Kyrš, M.; Pelčík, J.; Polanský, P. Collection of Czechoslovak Chemical Communications, Vol. 25, Issue 10 https://doi.org/10.1135/cccc19602642	journal	January 1960
The Removal of Cesium from Medium-Active Waste Solutions Blasius, E.; Nilles, K. -H. Radiochimica Acta, Vol. 35, Issue 3 https://doi.org/10.1524/ract.1984.35.3.173	journal	January 1984
Extraction of alkali metal cations from aqueous solutions by a crown ether carboxylic acid Strzelbicki, Jerzy.; Bartsch, Richard A. Analytical Chemistry, Vol. 53, Issue 12 https://doi.org/10.1021/ac00235a040	journal	October 1981
Extraction of alkali metals into nitrobenzene in the presence of univalent polyhedral borate anions Rais, J.; Selucký, P.; Kyrš, M. Journal of Inorganic and Nuclear Chemistry, Vol. 38, Issue 7 https://doi.org/10.1016/0022-1902(76)80156-X	journal	January 1976
Studies of the Size-Selective Extraction of Alkali Metal Ions by the Synergistic Extraction System, Crown Ether-DI(2-Ethylhexyl) Phosphoric Acid-Benzene Kinard, W. F.; Mcdowell, W. J.; Shoun, R. R. Separation Science and Technology, Vol. 15, Issue 4 https://doi.org/10.1080/01496398008076284	journal	May 1980
Extraction of Alkali Metals by 4-sec-Butyl-2-(α-methylbenzyl)phenol (BAMBP) Egan, B. Z.; Zingaro, Ralph A.; Benjamin, B. M. Inorganic Chemistry, Vol. 4, Issue 7 https://doi.org/10.1021/ic50029a030	journal	July 1965
Investigation of intermolecular association of 4-sec-butyl-2-(α-methylbenzyl)phenol (BAMBP) by use of dielectric and isopiestic measurements Roddy, J. W.; Coleman, C. F. Journal of Inorganic and Nuclear Chemistry, Vol. 35, Issue 12 https://doi.org/10.1016/0022-1902(73)80416-6	journal	December 1973
Extraction of Sodium and Cesium Polyoidides into Nitrobenzene Slater, Louis M. Nuclear Science and Engineering, Vol. 17, Issue 4 https://doi.org/10.13182/NSE63-A18450	journal	December 1963
The Removal of Cesium f r om Medium-Active Waste Solutions Blasius, E.; NlLLES, K. -H. Radiochimica Acta, Vol. 36, Issue 4 https://doi.org/10.1524/ract.1984.36.4.207	journal	January 1984
The Extraction of Cesium and Strontium from Acidic high Activity Nuclear Waste Using a Purex Process Compatible Organic Extractant Shuler, R. G.; Bowers, C. B.; Smith, J. E. Solvent Extraction and Ion Exchange, Vol. 3, Issue 5 https://doi.org/10.1080/07366298508918529	journal	October 1985
Crown Ethers as Solvent Extraction Reagents: Where do We Stand? Mcdowell, W. J. Separation Science and Technology, Vol. 23, Issue 12-13 https://doi.org/10.1080/01496398808075628	journal	October 1988
Crown ethers as size-selective synergists in solvent extraction systems: A new selectivity parameter Kinard, W. F.; McDowell, W. J. Journal of Inorganic and Nuclear Chemistry, Vol. 43, Issue 11 https://doi.org/10.1016/0022-1902(81)80648-3	journal	January 1981

Similar Records

Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions

Patent · 1998 · OSTI ID:872224

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions

Patent · 2000 · OSTI ID:873495

Radium separation through complexation by aqueous crown ethers and ion exchange or solvent extraction

Technical Report · 1997 · OSTI ID:554809

Related Subjects

05 NUCLEAR FUELS
CESIUM
CHELATING AGENTS
CROWN ETHERS
EXTRACTION
RADIOACTIVE WASTE PROCESSING
RECYCLING

Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions

Citation Formats

References (26)

Similar Records

Related Subjects