[PPN][Fe{sub 3}(CO){sub 9}(C{triple_bond}CH)] and [Fe{sub 3}(CO){sub 9}(C{triple_bond}COTi(THF){sub 4}Cl)] from the reaction of low-valent titanium with [Fe{sub 3}(CO){sub 9}(CCO)]{sup 2{minus}}
TiCl{sub 3}(DME){sub 1.5} (DME = 1,2-dimethoxyethane) and a Zn-Cu couple react with [PPN]{sub 2}[Fe{sub 3}(CO){sub 9}(CCO)] to give the new compound [PPN][Fe{sub 3}(CO){sub 9}(C{triple_bond}CH)] (1) (70% yield), a known compound [Fe{sub 3}(CO){sub 10}(CCH{sub 2})] (2) (9% yield), and another new compound [Fe{sub 3}(CO){sub 9}(CCOTi(THF){sub 4}Cl)] (3). Compound 1 was characterized by {sup 1}H and {sup 13}C NMR, IR, mass spectrometry, and X-ray crystallography. Compound 3 was characterized by IR, mass spectrometry, {sup 13}C NMR, and X-ray crystallography.
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-86ER13640
- OSTI ID:
- 329264
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 4 Vol. 18; ISSN ORGND7; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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