Calorimetric and spectroscopic characterization of zone refined and regrown lead iodide
- Fisk Univ., Nashville, TN (United States). Dept. of Physics
Lead iodide starting materials have been purified by vertical zone refining process. The purest materials of the zone-refined ingot, middle zone, were used for single crystal growth by Bridgman method. Differential scanning calorimetry, current-voltage and low temperature photoluminescence measurements were employed to investigate the effectiveness of zone refining process and as-grown crystal. The results showed that the materials from the middle section of zone-refined ingot is the purest, followed by first-to-freeze and last-to-freeze materials. No second phase and deviation from stoichiometry have been observed after zone refining process and Bridgman crystal growth method. The resistivities increase as the purity and crystallinity of materials increases. Cleavage of as-grown crystal did damage the surface and caused additional emission at 2.0 eV. This emission band was not observed after a 10% NaI solution etching.
- Sponsoring Organization:
- National Aeronautics and Space Administration, Washington, DC (United States)
- OSTI ID:
- 323868
- Report Number(s):
- CONF-971201-; TRN: 99:004400
- Resource Relation:
- Conference: 1997 fall meeting of the Materials Research Society, Boston, MA (United States), 1-5 Dec 1997; Other Information: PBD: 1998; Related Information: Is Part Of Semiconductors for room-temperature radiation detector applications 2; James, R.B. [ed.] [Sandia National Labs., Livermore, CA (United States)]; Schlesinger, T.E. [ed.] [Carnegie Mellon Univ., Pittsburgh, PA (United States)]; Siffert, P. [ed.] [Lab. PHASE/CNRS, Strasbourg (France)]; Dusi, W. [ed.] [Inst. TESRE/CNR, Bologna (Italy)]; Squillante, M.R. [ed.] [Radiation Monitoring Devices, Inc., Watertown, MA (United States)]; O`Connell, M. [ed.] [Dept. of Energy, Washington, DC (United States)]; Cuzin, M. [ed.] [LETI/CEA, Grenoble (France)]; PB: 681 p.; Materials Research Society symposium proceedings, Volume 487
- Country of Publication:
- United States
- Language:
- English
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