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Biomass gasification with air in fluidized bed: Reforming of the gas composition with commercial steam reforming catalysts

Journal Article · · Industrial and Engineering Chemistry Research
DOI:https://doi.org/10.1021/ie980254h· OSTI ID:321076
; ;  [1]
  1. Univ. Complutense of Madrid (Spain). Dept. of Chemical Engineering
Four commercial catalysts for steam reforming of higher hydrocarbons (naphthas) and three for steam reforming of light hydrocarbons are tested for hot gas clean up and upgrading in biomass gasification with air in fluidized bed. The catalysts used originate from four manufacturers: BASF, AG, ICI-Katalco, Haldor Topsoe a/s, and United Catalysts Inc. The work is performed in a small pilot plant (1--2 kg of biomass fed/h) with three reactors in series: gasifier, guard bed of dolomite, and full flow catalytic bed. Samples of gas are taken before and after the catalytic bed at different times-on-stream. It is shown how the H{sub 2}, CO, CO{sub 2}, CH{sub 4} and steam contents in the flue gas change because of the catalytic bed approaching contents near to the ones corresponding to the equilibrium state. Variations in the heating value of the gas and gas yield as a result of the catalytic bed are also reported.
OSTI ID:
321076
Journal Information:
Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 12 Vol. 37; ISSN IECRED; ISSN 0888-5885
Country of Publication:
United States
Language:
English

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