Persistence and distribution of 4-nonylphenol in water, sediment, macrophytes, and wall material of littoral enclosures

Conference · Sat Dec 31 04:00:00 EST 1994

OSTI ID:31769

Heinis, L J; Tunell, R; Liber, K ^[1]; Knuth, M L ^[2]

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1. Univ. of Wisconsin, Superior, WI (United States). Lake Superior Research Inst.
2. Environmental Protection Agency, Duluth, MN (United States). Environmental Research Lab.

Eighteen enclosures (5 m x 10 m) were constructed in the littoral zone of a 2-ha pond near Duluth, MN. Each enclosure consisted of 5 m of natural shoreline and three walls of an inert plastic. The enclosures had an average surface area of 31.9 m{sup 2} , an average depth of 0.6 m and an average water volume of 33.1 m{sup 3}. The enclosure waters were treated with the alkyl phenol ethoxylate precursor and degradation product 4-nonylphenol. Application was accomplished by sub-surface injection over a 20-day period with a 2 day frequency. Nominal aqueous concentrations were 0, 3, 30, 100 and 300 {mu}g/L. Concentrations of 4-nonylphenol were monitored during and after application in the water, sediment, macrophytes, and enclosure wall material. Average maximum water concentrations ranged from 96.5% of nominal to 62.0% of nominal and average minimum water concentrations ranged from 33.3% of nominal to 29.5% of nominal during the application period. Water concentrations decreased exponentially after application ended. Sediment concentrations during the application period were constant from 8 to 20 d and peak concentrations occurred 48 d after application began. Macrophyte concentrations peaked 21 d after initial application with a steady decline through 76 d. Enclosure wall material concentrations reached a peak 3 h before the final application. A gradual decline occurred until 34 d after initial application followed by a more rapid dissipation.

• OSTI ID: 31769
• Report Number(s): CONF-9410273--
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
56 BIOLOGY AND MEDICINE
APPLIED STUDIES
BIOLOGICAL ACCUMULATION
COASTAL WATERS
ECOLOGICAL CONCENTRATION
MINNESOTA
MONITORING
PHENOLS
PLANTS
WATER POLLUTION