Investigation of real-time microstructure evolution in steep thermal gradients using in-situ spatially resolved X-ray diffraction: A case study for Ti fusion welds

Journal Article · Thu Dec 24 04:00:00 EST 1998 · Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical

DOI:https://doi.org/10.1021/jp983045j· OSTI ID:315996

Ressler, T; Wong, J; Elmer, J W ^[1]

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1. Lawrence Livermore National Lab., CA (United States)

A recently developed spatially resolved X-ray diffraction (SRXRD) technique utilizing intense synchrotron radiation has been refined to yield phase and microstructural information down to 200 {micro}m in spatial extent in materials subjected to steep thermal gradients during processing. This SRXRD technique has been applied to map completely the phases and their solid-state transformation in the so-called heat-affected zone (HAZ) in titanium fusion welds in situ during the welding process. Detailed profile analysis of the SRXRD patterns revealed four principal microstructural regions at temperature in the vicinity of the HAZ surrounding the liquid weld pool: (i) a completely transformed {beta}-Ti zone 2--3 mm adjacent to the liquid weld pool; (ii) a mixed {alpha} + {beta}-it region surrounding the pure {beta}-Ti zone, (iii) a back-transformed {alpha}-Ti zone on the backside of the HAZ where pure {beta}-Ti once existed at temperature well above the {alpha} {r_arrow} {beta} transformation isotherm, and (iv) a more diffused region outside the HAZ where annealing and recrystallization of the {alpha}-it base metal occur. The high-temperature microstructures so derived corroborate well the expected transformation kinetics in pure titanium, and the observed phase transformation boundaries are in good agreement with those predicted from the transformation isotherms calculated from a simplified heat-flow model. Based on a detailed assessment of the SRXRD setup employed, improved experimentations such as a smaller beam spot emitted from third generation synchrotron sources, better mechanical stability (tighter scattering geometry), and use of an area detector would enable more quantitative structural information for future phase dynamics studies exemplified by this work.

• Sponsoring Organization: USDOE, Washington, DC (United States); Alexander von Humboldt-Stiftung, Bonn (Germany)
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 315996
• Journal Information: Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical, Journal Name: Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical Journal Issue: 52 Vol. 102; ISSN 1089-5647; ISSN JPCBFK
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
CRYSTAL-PHASE TRANSFORMATIONS
EXPERIMENTAL DATA
HEAT AFFECTED ZONE
LIQUID METALS
MICROSTRUCTURE
TEMPERATURE GRADIENTS
TITANIUM
WELDED JOINTS
X-RAY DIFFRACTION