Photochemical solar cells based on dye-sensitization of nanocrystalline TiO{sub 2}
- National Renewable Energy Lab., Golden, CO (United States)
A photoelectrochemical solar cell that is based on the dye-sensitization of thin nanocrystalline films of TiO{sub 2} (anatase) nanoparticles in contact with a non-aqueous liquid electrolyte is described. The cell, fabricated at NREL, shows a conversion efficiency of {approximately} 9.2% at AM1.5, which approaches the best reported value of 10--11% by Graetzel at EPFL in Lausanne, Switzerland. The femtosecond (fs) pump-probe spectroscopy has been used to time resolve the injection of electrons into the conduction band of nanocrystalline TiO{sub 2} films under ambient conditions following photoexcitation of the adsorbed Ru(II)-complex dye. The measurement indicates an instrument-limited {minus}50 fs upper limit on the electron injection time. The authors also report the sensitization of nanocrystalline TiO{sub 2} by a novel iron-based dye, CIS-[Fe{sup II}(2,2{prime}-bipyridine-4,4,{prime}-dicarboxylic acid){sub 2}(CN){sub 2}], a chromophore with an extremely short-lived, nonemissive excited state. The dye also exhibits a unique band selective sensitization through one of its two absorption bands. The operational principle of the device has been studied through the measurement of electric field distribution within the device structure and studies on the pH dependence of dye-redox potential. The incorporation of WO{sub 3}-based electrochromic layer into this device has led to a novel photoelectrochromic device structure for smart window application.
- Research Organization:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- OSTI ID:
- 305635
- Report Number(s):
- NREL/TP-520-25101; CONF-980735-PROC.; ON: DE98007497; TRN: IM9906%%315
- Resource Relation:
- Conference: 2. world conference and exhibition on photovoltaic solar energy conversion, Vienna (Austria), 6-10 Jul 1998; Other Information: PBD: Sep 1998; Related Information: Is Part Of NCPV preprints for the 2. world conference on photovoltaic solar energy conversion; PB: 142 p.
- Country of Publication:
- United States
- Language:
- English
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