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Modeling of substrate bias effect on the compositional variations in sputtered-deposited TiB{sub 2+x} diffusion barrier thin films

Book ·
OSTI ID:305588
; ;  [1]
  1. Ben-Gurion Univ. of the Negev, Beer-Sheva (Israel). Dept. of Materials Engineering
Sputter-deposited titanium boride diffusion barrier layers have been found to be boron enriched when r.f. substrate bias was applied. In the present experiments titanium boride was deposited by co-sputtering from Ti and B pure targets in Ar discharge and the voltage of r.f. self-bias was in the range of 100--250 V. Films deposited were found by Auger electron spectroscopy to be B enriched with increasing bias voltage at constant Ti and B sputtering rates. A model of the sputter-deposition conditions was developed to predict the composition and the thickness of the growing film. The model explains the experimental results indicating that B enrichment is mainly a result of differential resputtering of the components from the growing film by energetic Ar ions capture from the r.f. discharge.
OSTI ID:
305588
Report Number(s):
CONF-980405--
Country of Publication:
United States
Language:
English

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