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Title: Predictive models for determination of pitting corrosion versus inhibitor concentrations and temperature for radioactive sludge in carbon steel waste tanks

Journal Article · · Corrosion
DOI:https://doi.org/10.5006/1.3283962· OSTI ID:305361
;  [1];  [2]
  1. Univ. of South Carolina, Aiken, SC (United States). Dept. of Mathematical Sciences and Engineering
  2. Westinghouse Savannah River Co., Aiken, SC (United States)

Statistical models were developed to predict the occurrence of pitting corrosion in carbon steel (CS) waste storage tanks exposed to radioactive nuclear waste. Levels of nitrite (NO{sub 2}{sup {minus}}) concentrations necessary to inhibit pitting at various temperatures and nitrate (NO{sub 3}{sup {minus}}) concentrations were determined experimentally via electrochemical polarization and coupon immersion corrosion tests. Models for the pitting behavior were developed based upon various statistical analyses of the experimental data. Freed-forward, artificial neural network (ANN) models, trained using the back-propagation of error algorithm, more accurately predicted conditions at which pitting occurred than the logistic regression models development using the same data.

Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC09-89SR18035
OSTI ID:
305361
Journal Information:
Corrosion, Vol. 55, Issue 1; Other Information: PBD: Jan 1999
Country of Publication:
United States
Language:
English