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Effect of CdS annealing in (CdCl{sub 2} + CdS) atmosphere on CdTe cells

Conference ·
OSTI ID:304314
; ; ;  [1];  [2]
  1. Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering
  2. Korea Univ., Seoul (Korea, Republic of). Dept. of Materials Science and Engineering

To increase grain size, solution-grown CdS films were annealed at 560 C in a (CdCl{sub 2} + CdS) atmosphere, instead of CdCl{sub 2} only environment. CdS was used to prevent the evaporation of CdS from the films. After 5 min annealing, the grain size increased from 10 nm to 100 nm and the surface morphology was very smooth and densely packed. The optical transmittance was greatly improved near E{sub g}, compared to that of CdS films annealed at 400 C for 30 min in H{sub 2}. The efficiency of the CdTe solar cell was improved by fabricating with the CdS layer annealed in a (CdCl{sub 2} + CdS) atmosphere. The increase of the efficiency was mainly due to the increase of fill factor, which might be due to the decrease of defects at CdTe bulk and the CdS/CdTe interface.

OSTI ID:
304314
Report Number(s):
CONF-970953--
Country of Publication:
United States
Language:
English

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