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Title: Transportable vitrification system demonstration on mixed waste. Revision 1

Conference ·
OSTI ID:304002
;  [1];  [2];  [3]
  1. Westinghouse Savannah River Co., Aiken, SC (United States)
  2. Lockheed Martin Hanford Corp., Richland, WA (United States)
  3. Bechtel Jacobs Co., Oak Ridge, TN (United States)

The Transportable Vitrification System (TVS) is a large scale, fully integrated, vitrification system for the treatment of low-level and mixed wastes in the form of sludges, soils, incinerator ash, and many other waste streams. It was demonstrated on surrogate waste at Clemson University and at the Oak Ridge Reservation (ORR) prior to treating actual mixed waste. Treatment of a combination of dried B and C Pond sludge and CNF sludge was successfully demonstrated at ORR in 1997. The demonstration produced 7,616 kg of glass from 7,328 kg of mixed wastes with a 60% reduction in volume. Glass formulations for the wastes treated were developed using a combination of laboratory crucible studies with the actual wastes and small melter studies at Clemson with both surrogate and actual wastes. Initial characterization of the B and C Pond sludge had not shown the presence of carbon or fluoride, which required a modified glass formulation be developed to maintain proper glass redox and viscosity. The CNF sludge challenges the glass formulations due to high levels of phosphate and iron. The demonstration was delayed several times by permitting problems, a glass leak, and electrical problems. The demonstration showed that the two wastes could be successfully vitrified, although the design glass production rate was not achieved. The glass produced met the Universal Treatment Standards and the emissions from the TVS were well within the allowable permit limits.

Research Organization:
Westinghouse Savannah River Co., Savannah River Site, Aiken, SC (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC09-96SR18500
OSTI ID:
304002
Report Number(s):
WSRC-MS-97-00821-Rev.1; CONF-980905-; ON: DE99001339; TRN: 99:003144
Resource Relation:
Conference: SPECTRUM `98: nuclear and hazardous waste management international topical meeting, Denver, CO (United States), 13-18 Sep 1998; Other Information: PBD: 22 Apr 1998
Country of Publication:
United States
Language:
English