To thread or not to thread: Reaction of uranyl (UO22+) with two Aza-crown macrocycles

Godinho, Gabriella S.; Lee, Kevin K.; Feng, Qien; Wu, Guang; Wilson, Justin J.; Hayton, Trevor W.

doi:10.1016/j.poly.2025.117935

To thread or not to thread: Reaction of uranyl (UO₂²⁺) with two Aza-crown macrocycles

Journal Article · Mon Dec 15 00:00:00 EST 2025 · Polyhedron

DOI:https://doi.org/10.1016/j.poly.2025.117935· OSTI ID:3014812

Godinho, Gabriella S. ^[1]; Lee, Kevin K. ^[1]; Feng, Qien ^[1]; Wu, Guang ^[1]; Wilson, Justin J. ^[1]; Hayton, Trevor W. ^[1]

University of California, Santa Barbara, CA (United States)

The complexation of the uranyl ion (UO₂²⁺) by macrocyclic ligands is hindered by the rigidly enforced trans orientation of its oxo ligands. To further investigate this coordination chemistry challenge, here we investigate the reactivity of UO₂²⁺ with two different 18-membered aza-crown macrocycles, diaza-dibenzo-18-crown-6 (DADBC) and 7,16-bis(N-methylacetamide)diaza-18-crown-6 (BAM). The reaction of uranyl triflate, [UO₂(OTf)₂(THF)₃], with DADBC in toluene afforded [UO₂(DADBC)][OTf]₂, in which the UO₂²⁺ ion is fully encapsulated by the macrocycle. This conclusion was supported by NMR, UV–Vis, IR, and Raman spectroscopies, as well as single-crystal X-ray crystallography. Attempts to form the in-macrocycle complex of BAM, however, were unsuccessful. Here, the reaction of BAM with [UO₂(OTf)₂(THF)₃] in THF/CH₂Cl₂ unexpectedly afforded crystals of [H₂BAM][OTf]₂, where the protons are derived from solvate water in the BAM crystal lattice.

View Accepted Manuscript (DOE)

Research Organization:: University of California, Santa Barbara, CA (United States)

Sponsoring Organization:: National Institutes of Health (NIH); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: SC0001861

OSTI ID:: 3014812

Journal Information:: Polyhedron, Journal Name: Polyhedron Vol. 285; ISSN 0277-5387

Publisher:: Elsevier BVCopyright Statement

Country of Publication:: United States

Language:: English

References (75)

Hexaphyrin(1.0.1.0.0.0): An Expanded Porphyrin Ligand for the Actinide Cations Uranyl (UO22+) and Neptunyl (NpO2+) Sessler, Jonathan L.; Seidel, Daniel; Vivian, Anne E. Angewandte Chemie International Edition, Vol. 40, Issue 3 https://doi.org/10.1002/1521-3773(20010202)40:3<591::AID-ANIE591>3.0.CO;2-0	journal	January 2001
Subtleties with Sulfur: Calixarenes as Uranophiles Asfari, Zouhair; Bilyk, Alexander; Dunlop, John W. C. Angewandte Chemie International Edition, Vol. 40, Issue 4 https://doi.org/10.1002/1521-3773(20010216)40:4<721::AID-ANIE7210>3.0.CO;2-G	journal	February 2001
Single-Electron Uranyl Reduction by a Rare-Earth Cation Arnold, Polly L.; Hollis, Emmalina; White, Fraser J. Angewandte Chemie International Edition, Vol. 50, Issue 4 https://doi.org/10.1002/anie.201005511	journal	December 2010
Oxo Group Protonation and Silylation of Pentavalent Uranyl Pacman Complexes Arnold, Polly L.; Pécharman, Anne-Frédérique; Love, Jason B. Angewandte Chemie International Edition, Vol. 50, Issue 40 https://doi.org/10.1002/anie.201104359	journal	August 2011
Controlled Deprotection and Reorganization of Uranyl Oxo Groups in a Binuclear Macrocyclic Environment Jones, Guy M.; Arnold, Polly L.; Love, Jason B. Angewandte Chemie International Edition, Vol. 51, Issue 50 https://doi.org/10.1002/anie.201207609	journal	November 2012
Ligand‐Directed Actinide Oxo‐Bond Manipulation in Actinyl Thiacalix[4]arene Complexes Pyrch, Mikaela M.; Meyer, Rachel L.; Rajeshkumar, Thayalan Angewandte Chemie International Edition, Vol. 64, Issue 15 https://doi.org/10.1002/anie.202422974	journal	February 2025
Hexaalkyl Terpyrrole: A New Building Block for the Preparation of Expanded Porphyrins Sessler, Jonathan L.; Weghorn, Steven J.; Hiseada, Yoshio Chemistry - A European Journal, Vol. 1, Issue 1 https://doi.org/10.1002/chem.19950010110	journal	April 1995
The Effect of the Equatorial Environment on Oxo-Group Silylation of the Uranyl Dication: A Computational Study Yahia, Ahmed; Arnold, Polly L.; Love, Jason B. Chemistry - A European Journal, Vol. 16, Issue 16 https://doi.org/10.1002/chem.200902991	journal	March 2010
Oxo-Group-14-Element Bond Formation in Binuclear Uranium(V) Pacman Complexes Jones, Guy M.; Arnold, Polly L.; Love, Jason B. Chemistry - A European Journal, Vol. 19, Issue 31 https://doi.org/10.1002/chem.201301067	journal	June 2013
f-Element/crown ether complexes, 11. Preparation and structural characterization of [UO2(OH2)5] [ClO4]2�3(15-crown-5)�CH3CN and [UO2(OH2)5] [ClO4]2�2(18-crown-6)�2 CH3CN�H2O Rogers, Robin D.; Kurihara, Lynn K.; Benning, Matthew M. Journal of Inclusion Phenomena, Vol. 5, Issue 5 https://doi.org/10.1007/BF00663006	journal	October 1987
Selective complexation of UO 2 2+ by the calix[6]arene6? anion: Structure and hydration studied by molecular dynamics simulations Guilbaud, P.; Wipff, G. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Vol. 16, Issue 2 https://doi.org/10.1007/BF00709150	journal	January 1993
Macrocycle complexation chemistry. 37. The isolation and crystallographic characterization of the U4+ and UO2+ extraction complexes [(H5O2)(dicyclohexano-24-crown-8)]2[U02Cl4]?MeOH and [(H5O2) (dicyclohexano-24-crown-8)]2[UCl6]?MeOH Rogers, Robin D.; Benning, Matthew M. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Vol. 11, Issue 2 https://doi.org/10.1007/BF01153296	journal	September 1991
Synergistic extraction of Am(III), Th(IV) and U(VI) by PMBP and crown ethers Yonezawa, C.; Choppin, G. R. Journal of Radioanalytical and Nuclear Chemistry Articles, Vol. 134, Issue 1 https://doi.org/10.1007/BF02047286	journal	November 1989
Infrared spectra of some uranyl nitrate complexes Bullock, J. I. Journal of Inorganic and Nuclear Chemistry, Vol. 29, Issue 9 https://doi.org/10.1016/0022-1902(67)80280-X	journal	September 1967
Mid-, far-infrared and raman spectra of uranyl complexes in aqueous solutions Gál, M.; Goggin, P. L.; Mink, J. Journal of Molecular Structure, Vol. 114 https://doi.org/10.1016/0022-2860(84)87186-0	journal	January 1984
Vibrational dynamics and phase transition in uranyl Nitrate Dihydrate (Dideuterate), UO2(NO3)2·2H2O (2D2O) through Raman spectroscopy Khulbe, P. K.; Ttripathi, Renu; Bist, H. D. Journal of Physics and Chemistry of Solids, Vol. 53, Issue 5 https://doi.org/10.1016/0022-3697(92)90202-O	journal	May 1992
Actinide expanded porphyrin complexes Sessler, J. L.; Vivian, A. E.; Seidel, D. Coordination Chemistry Reviews, Vol. 216-217 https://doi.org/10.1016/S0010-8545(00)00395-7	journal	June 2001
Crystal and molecular structure of uranyl nitrate trimethylphosphate Agostini, Giancarlo; Giacometti, Giovanni; Clemente, Dore A. Inorganica Chimica Acta, Vol. 62 https://doi.org/10.1016/S0020-1693(00)88507-2	journal	January 1982
Anhydrous uranyl crown-ether complexes. 1H nuclear magnetic resonance and x-ray study Folcher, Gerard; Charpin, Pierrette; Costes, Rose-Marie Inorganica Chimica Acta, Vol. 34 https://doi.org/10.1016/S0020-1693(00)94682-6	journal	January 1979
Novel, terpyrrole-containing, aromatic expanded porphyrins Sessler, Jonathan L.; Seidel, Daniel; Bucher, Christophe Tetrahedron, Vol. 57, Issue 17 https://doi.org/10.1016/S0040-4020(01)00243-5	journal	April 2001
Complexation of the uranyl ion by crown ethers, diaza-crown ethers and analogous acyclic ligands in solution Lagrange, J.; Metabanzoulou, J. P.; Fux, P. Polyhedron, Vol. 8, Issue 18 https://doi.org/10.1016/S0277-5387(00)81251-6	journal	January 1989
The crystal and molecular structure of UO2(NO3)2[Ph2P(O)CH2C(O)Ph]2 and its role in the solvent extraction of the uranyl ion Babecki, Ryszard; Platt, Andrew W. G.; Tebby, John C. Polyhedron, Vol. 8, Issue 10 https://doi.org/10.1016/S0277-5387(00)86536-5	journal	January 1989
Crystal structures of the dicyclohexyl-(18-crown-6) uranyl perchlorate complex and of its hydrolysis product Navaza, A.; Villain, F.; Charpin, P. Polyhedron, Vol. 3, Issue 2 https://doi.org/10.1016/S0277-5387(00)88043-2	journal	January 1984
Oxo ligand functionalization in the uranyl ion (UO22+) Fortier, Skye; Hayton, Trevor W. Coordination Chemistry Reviews, Vol. 254, Issue 3-4 https://doi.org/10.1016/j.ccr.2009.06.003	journal	February 2010
Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy Lu, Grace; Haes, Amanda J.; Forbes, Tori Z. Coordination Chemistry Reviews, Vol. 374 https://doi.org/10.1016/j.ccr.2018.07.010	journal	November 2018
Coordination of bistriflimide and triflate to the uranyl bis(diphenylphosphino)methane dication, {UO2(DPPMO2)2}2+ Cornet, Stéphanie M.; May, Iain; Redmond, Michael P. Polyhedron, Vol. 28, Issue 2 https://doi.org/10.1016/j.poly.2008.10.070	journal	February 2009
A combined experimental and quantum chemical studies on the structure and binding preferences of picolinamide based ligands with uranyl nitrate Das, Debasish; Joshi, Meenakshi; Kannan, Shanmugaperumal Polyhedron, Vol. 171 https://doi.org/10.1016/j.poly.2019.08.005	journal	October 2019
Evaluating Best Practices in Raman Spectral Analysis for Uranium Speciation and Relative Abundance in Aqueous Solutions Lu, Grace; Forbes, Tori Z.; Haes, Amanda J. Analytical Chemistry, Vol. 88, Issue 1 https://doi.org/10.1021/acs.analchem.5b03038	journal	December 2015
Coordination of Uranyl to the Redox-Active Calix[4]pyrrole Ligand Kent, Greggory T.; Murillo, Jesse; Wu, Guang Inorganic Chemistry, Vol. 59, Issue 12 https://doi.org/10.1021/acs.inorgchem.0c01224	journal	June 2020
Oxo Ligand Substitution in a Cationic Uranyl Complex: Synergistic Interaction of an Electrophile and a Reductant Pedrick, Elizabeth A.; Wu, Guang; Hayton, Trevor W. Inorganic Chemistry, Vol. 54, Issue 14 https://doi.org/10.1021/acs.inorgchem.5b01077	journal	July 2015
Perturbation of the O–U–O Angle in Uranyl by Coordination to a 12-Membered Macrocycle Pedrick, Elizabeth A.; Schultz, Jason W.; Wu, Guang Inorganic Chemistry, Vol. 55, Issue 11 https://doi.org/10.1021/acs.inorgchem.6b00799	journal	May 2016
Uranyl Coordination by the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene Pedrick, Elizabeth A.; Assefa, Mikiyas K.; Wakefield, Megan E. Inorganic Chemistry, Vol. 56, Issue 11 https://doi.org/10.1021/acs.inorgchem.7b00700	journal	May 2017
Uranyl/12-crown-4 Ether Complexes and Derivatives: Structural Characterization and Isomeric Differentiation Jian, Jiwen; Hu, Shu-Xian; Li, Wan-Lu Inorganic Chemistry, Vol. 57, Issue 7 https://doi.org/10.1021/acs.inorgchem.8b00306	journal	December 2017
Oxidation of the 14-Membered Macrocycle Dibenzotetramethyltetraaza[14]annulene upon Ligation to the Uranyl Ion Assefa, Mikiyas K.; Pedrick, Elizabeth A.; Wakefield, Megan E. Inorganic Chemistry, Vol. 57, Issue 14 https://doi.org/10.1021/acs.inorgchem.8b00966	journal	June 2018
Coordination Structures of Uranium(VI) and Plutonium(IV) in Organic Solutions with Amide Derivatives Berger, Clémence; Marie, Cécile; Guillaumont, Dominique Inorganic Chemistry, Vol. 59, Issue 3 https://doi.org/10.1021/acs.inorgchem.9b03024	journal	January 2020
Molecular and Crystal Structures of Uranyl Nitrate Complexes with N-Alkylated 2-Pyrrolidone Derivatives: Design and Optimization of Promising Precipitant for Uranyl Ion Takao, Koichiro; Noda, Kyoko; Morita, Yasuji Crystal Growth & Design, Vol. 8, Issue 7 https://doi.org/10.1021/cg7012254	journal	May 2008
Synthesis and structural elucidation of novel uranyl-crown ether compounds isolated from nitric, hydrochloric, sulfuric, and acetic acids Rogers, Robin D.; Bond, Andrew H.; Hipple, William G. Inorganic Chemistry, Vol. 30, Issue 12 https://doi.org/10.1021/ic00012a021	journal	June 1991
Synthesis and x-ray characterization of a uranyl(VI) Schiff base complex derived from a 2:2 condensation product of 3,4-diethylpyrrole-2,5-dicarbaldehyde and 1,2-diamino-4,5-dimethoxybenzene Sessler, Jonathan L.; Mody, Tarak D.; Lynch, Vincent Inorganic Chemistry, Vol. 31, Issue 4 https://doi.org/10.1021/ic00030a001	journal	February 1992
Coordination Trends in Alkali Metal Crown Ether Uranyl Halide Complexes: The Series [A(Crown)] ₂ [UO ₂ X ₄ ] Where A = Li, Na, K and X = Cl, Br Danis, Janet A.; Lin, Mavis R.; Scott, Brian L. Inorganic Chemistry, Vol. 40, Issue 14 https://doi.org/10.1021/ic0011056	journal	July 2001
Discussion on the complexing ability of the uranyl ion with several crown ethers and cryptands in water and in propylene carbonate Brighli, Mohammed; Fux, Pierre; Lagrange, Janine Inorganic Chemistry, Vol. 24, Issue 1 https://doi.org/10.1021/ic00195a016	journal	January 1985
Uranyl Complexation by a Schiff-Base, Polypyrrolic Macrocycle Arnold, Polly L.; Blake, Alexander J.; Wilson, Claire Inorganic Chemistry, Vol. 43, Issue 26 https://doi.org/10.1021/ic0487070	journal	December 2004
Steric Effects on Uranyl Complexation: Synthetic, Structural, and Theoretical Studies of Carbamoyl Pyrazole Compounds of the Uranyl(VI) Ion Das, Debasish; Kannan, Shanmugaperumal; Maity, Dilip K. Inorganic Chemistry, Vol. 51, Issue 8 https://doi.org/10.1021/ic300398a	journal	April 2012
Crown Ether Complexes of Uranyl, Neptunyl, and Plutonyl: Hydration Differentiates Inclusion versus Outer Coordination Gong, Yu; Gibson, John K. Inorganic Chemistry, Vol. 53, Issue 11 https://doi.org/10.1021/ic500724q	journal	May 2014
Structure of di-.mu.-aquo-bis(dioxobis(nitrato)uranium(VI)) diimidazole, [UO2 (NO3)2(H2O)].2C3H4N2, a water bridged dimer of uranyl nitrate Perry, Dale L.; Ruben, Helena; Templeton, David H. Inorganic Chemistry, Vol. 19, Issue 4 https://doi.org/10.1021/ic50206a058	journal	April 1980
The Role of Peripheral Alkyl Substituents: A Theoretical Study of Substituted and Unsubstituted Uranyl Isoamethyrin Complexes Shamov, Grigory A.; Schreckenbach, Georg Inorganic Chemistry, Vol. 47, Issue 3 https://doi.org/10.1021/ic701192t	journal	January 2008
Crown Ether Inclusion Complexes of the Early Actinide Elements, [AnO ₂ (18-crown-6)] ^{n +} , An = U, Np, Pu and n = 1, 2: A Relativistic Density Functional Study Shamov, Grigory A.; Schreckenbach, Georg; Martin, Richard L. Inorganic Chemistry, Vol. 47, Issue 5 https://doi.org/10.1021/ic7015403	journal	March 2008
Hydration of uranyl (UO22+) cation and its nitrate ion and 18-crown-6 adducts studied by molecular dynamics simulations Guilbaud, P.; Wipff, G. The Journal of Physical Chemistry, Vol. 97, Issue 21 https://doi.org/10.1021/j100123a037	journal	May 1993
Uranylpentaphyrin: an actinide complex of an expanded porphyrin Burrell, Anthony K.; Hemmi, Gregory; Lynch, Vincent Journal of the American Chemical Society, Vol. 113, Issue 12 https://doi.org/10.1021/ja00012a053	journal	June 1991
Kinetics and mechanisms of complex formation of uranyl ion with 18-crown-6 and diaza-18-crown-6 ligands in propylene carbonate Fux, Pierre; Lagrange, Janine; Lagrange, Philippe Journal of the American Chemical Society, Vol. 107, Issue 21 https://doi.org/10.1021/ja00307a017	journal	October 1985
Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations Arnold, Polly L.; Patel, Dipti; Blake, Alexander J. Journal of the American Chemical Society, Vol. 128, Issue 30 https://doi.org/10.1021/ja0634167	journal	August 2006
Oxo-Functionalization and Reduction of the Uranyl Ion through Lanthanide-Element Bond Homolysis: Synthetic, Structural, and Bonding Analysis of a Series of Singly Reduced Uranyl–Rare Earth 5f ¹ -4f ⁿ Complexes Arnold, Polly L.; Hollis, Emmalina; Nichol, Gary S. Journal of the American Chemical Society, Vol. 135, Issue 10 https://doi.org/10.1021/ja308993g	journal	March 2013
Uranium-Mediated Peroxide Activation and a Precursor toward an Elusive Uranium cis-Dioxo Fleeting Intermediate Hartline, Douglas R.; Löffler, Sascha T.; Fehn, Dominik Journal of the American Chemical Society, Vol. 145, Issue 16 https://doi.org/10.1021/jacs.2c12868	journal	April 2023
Synthesis, Isolation, and Study of Heterobimetallic Uranyl Crown Ether Complexes Golwankar, Riddhi R.; Ervin, Alexander C.; Makoś, Małgorzata Z. Journal of the American Chemical Society, Vol. 146, Issue 14 https://doi.org/10.1021/jacs.3c12075	journal	March 2024
Determination of the Molecular Structures of Ferric Enterobactin and Ferric Enantioenterobactin Using Racemic Crystallography Johnstone, Timothy C.; Nolan, Elizabeth M. Journal of the American Chemical Society, Vol. 139, Issue 42 https://doi.org/10.1021/jacs.7b09375	journal	October 2017
Redox-Inactive Metal Cations Modulate the Reduction Potential of the Uranyl Ion in Macrocyclic Complexes Kumar, Amit; Lionetti, Davide; Day, Victor W. Journal of the American Chemical Society, Vol. 142, Issue 6 https://doi.org/10.1021/jacs.9b11903	journal	January 2020
Actinyls in Expanded Porphyrin: A Relativistic Density-Functional Study Liao, Meng-Sheng; Kar, Tapas; Scheiner, Steve The Journal of Physical Chemistry A, Vol. 108, Issue 15 https://doi.org/10.1021/jp036927d	journal	February 2004
Electronic Structure and Bonding in Actinyl Ions and their Analogs Denning, Robert G. The Journal of Physical Chemistry A, Vol. 111, Issue 20 https://doi.org/10.1021/jp071061n	journal	May 2007
Synthesis and crystal structure of supramolecular adduct of tetranuclear uranyl chloride aquacomplex with macrocyclic cavitand cucurbituril Gerasko, O. A.; Samsonenko, D. G.; Sharonova, A. A. Russian Chemical Bulletin, Vol. 51, Issue 2 https://doi.org/10.1023/A:1015476215012	journal	February 2002
Reduction and selective oxo group silylation of the uranyl dication Arnold, Polly L.; Patel, Dipti; Wilson, Claire Nature, Vol. 451, Issue 7176 https://doi.org/10.1038/nature06467	journal	January 2008
Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation Arnold, Polly L.; Jones, Guy M.; Odoh, Samuel O. Nature Chemistry, Vol. 4, Issue 3 https://doi.org/10.1038/nchem.1270	journal	February 2012
Uranyl oxo activation and functionalization by metal cation coordination Arnold, Polly L.; Pécharman, Anne-Frédérique; Hollis, Emmalina Nature Chemistry, Vol. 2, Issue 12 https://doi.org/10.1038/nchem.904	journal	November 2010
Electronic structure and characterization of a uranyl di-15-crown-5 complex with an unprecedented sandwich structure Hu, Shu-Xian; Gibson, John K.; Li, Wan-Lu Chemical Communications, Vol. 52, Issue 86 https://doi.org/10.1039/C6CC07205D	journal	January 2016
Characterization of the binding of six actinyls AnO ₂ ^2+/+ (An = U/Np/Pu) with three expanded porphyrins by density functional theory Yang, Meixiu; Ding, Wanjian; Wang, Dongqi New Journal of Chemistry, Vol. 41, Issue 1 https://doi.org/10.1039/C6NJ01615D	journal	January 2017
Understanding the origins of O _yl –U–O _yl bending in the uranyl (UO ₂ ²⁺ ) ion Hayton, Trevor W. Dalton Transactions, Vol. 47, Issue 4 https://doi.org/10.1039/C7DT04123C	journal	January 2018
Macrocyclic control of electron transfer to high valent uranium in heterobimetallic complexes Kumar, Amit; Golwankar, Riddhi R.; Pyrch, Mikaela M. F. Dalton Transactions, Vol. 54, Issue 20 https://doi.org/10.1039/D4DT03503H	journal	January 2025
Synthesis and characterization of an oxasapphyrin-uranyl complex Sessler, Jonathan L.; Gebauer, Andreas Chemical Communications, Issue 17 https://doi.org/10.1039/a803975e	journal	January 1998
Novel unidentate co-ordination of a crown ether and of a polyethylene glycol to uranium(VI) Rogers, Robin D.; Benning, Matthew M.; Etzenhouser, Russell D. Journal of the Chemical Society, Chemical Communications, Issue 20 https://doi.org/10.1039/c39890001586	journal	January 1989
Actinide complexes of the calixarenes. Part 1. Syntheses and crystal structures of bis(homo-oxa)-p-tert-butylcalix[4]arene and its uranyl ion complex Harrowfield, Jack M.; Ogden, Mark I.; White, Allan H. Journal of the Chemical Society, Dalton Transactions, Issue 4 https://doi.org/10.1039/dt9910000979	journal	January 1991
Étude cinétique de la complexation de l'ion uranyle par l'éther-couronne 18C6 dans l'acétonitrile Lagrange, Janine; Metabanzoulou, Jean-Pierre; Lagrange, Philippe Journal de Chimie Physique, Vol. 86 https://doi.org/10.1051/jcp/19898601369	journal	January 1989
Evidence of the Uranium iii and Uranyl Complexation by Macrocycles From Exafs Dejean, A.; Charpin, P.; Folcher, G. Le Journal de Physique Colloques, Vol. 47, Issue C8 https://doi.org/10.1051/jphyscol:19868122	journal	December 1986
Synthesis and Structural Characterization of the Monodentate 12-Crown-4 And Hexaethylene Glycol Complexes of Uranium(VI): [UO ₂ Cl ₂ (OH ₂ ) ₂ (12-CROWN-4)].12-Crown-4 And UO ₂ Cl ₂ (OH ₂ ) ₂ (Hexaethylene Glycol) Rogers, Robin D.; Benning, Matthew M.; Etzenhouser, Russell D. Journal of Coordination Chemistry, Vol. 26, Issue 4 https://doi.org/10.1080/00958979209407932	journal	January 1992
Röntgenstrukturanalyse von diaquadinitratodioxouran(VI)–1,4,7,10,13-pentaoxacyclopentadecan Gutberlet, T.; Dreissig, W.; Luger, P. Acta Crystallographica Section C Crystal Structure Communications, Vol. 45, Issue 8 https://doi.org/10.1107/S0108270188009771	journal	August 1989
Structure of bis(ε-caprolactam)dinitratodioxouranium(VI) Cao, Z.; Wang, H.; Gu, J. Acta Crystallographica Section C Crystal Structure Communications, Vol. 49, Issue 11 https://doi.org/10.1107/S0108270193004536	journal	November 1993
Pentaaquadioxouranium(VI) triflate–18-crown-6 Deshayes, L.; Keller, N.; Lance, M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 50, Issue 10 https://doi.org/10.1107/S0108270193013745	journal	October 1994
An Inclusion Complex of Uranyl in a Diazacrown: (Diaza-18-crown-6)2+.2CF3SO3− and [UO2(diaza-18-crown-6)]+.CF3SO3− Thuéry, P.; Keller, N.; Lance, M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 51, Issue 5 https://doi.org/10.1107/S0108270194006037	journal	May 1995

Similar Records

Synthesis and characterization of a chiral, aza-15-crown-5-functionalized ferrocenyldiphosphine ligand for asymmetric catalysis

Journal Article · Sun Mar 19 23:00:00 EST 2000 · Organometallics · OSTI ID:20050906

Synthesis, Isolation, and Study of Heterobimetallic Uranyl Crown Ether Complexes

Journal Article · Wed Mar 27 20:00:00 EDT 2024 · Journal of the American Chemical Society · OSTI ID:2438924

Related Subjects

Actinide
Macrocycle
NMR spectroscopy
Uranyl
X-ray crystallography

To thread or not to thread: Reaction of uranyl (UO22+) with two Aza-crown macrocycles

Citation Formats

References (75)

Similar Records

Related Subjects

To thread or not to thread: Reaction of uranyl (UO₂²⁺) with two Aza-crown macrocycles