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U.S. Department of Energy
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Advanced PEM Electrolyzer Membrane for Hydrogen Crossover Mitigation

Technical Report ·
DOI:https://doi.org/10.2172/3014224· OSTI ID:3014224
An unintended reaction in the electrochemical conversion of water to hydrogen in proton exchange membrane (PEM) electrolyzers is the crossover of hydrogen from the anode to the oxygen-containing cathode through the membrane, creating hydrogen losses and safety concerns. Efforts to date have focused on embedding platinum catalysts in perfluorosulfonic (PFSA) membranes to convert H2 to protons. The objective of this project is to design and develop hydrocarbon (HC) proton exchange membranes (PEMs) that can help overcome the risk of high H2 crossover in current PEM electrolyzer (ELX) stacks by designing and optimizing the gas recombination catalyst (GRC) within the membrane and membrane electrode assembly (MEA) structure.
Research Organization:
Plug Power Inc.; Washington University in St. Louis; Rensselaer Polytechnic Institute; Ionomr Innovations Inc.
Sponsoring Organization:
Hydrogen and Fuel Cell Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Contributing Organization:
Washington University in St. Louis; Rensselaer Polytechnic Institute; Ionomr Innovations Inc.
DOE Contract Number:
EE0011328;
OSTI ID:
3014224
Report Number(s):
DOE-PLUG-11328-Final
Country of Publication:
United States
Language:
English

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